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SAURASHTRA UNIVtrR.SXTY B. Sc. SEMESTEIT. - IrI cHEMISTRY [C-301 I SYLLABT]S
: Inorganic Chemistry
1.
Wave Mechanics.
Coordination).
2.
Chemistry of Lanthanide Elements.
'r
Uses of Lanthanicles ct their Conrpouncis.
Unit II : Organic Chemistry 1.
Aldehydes and
Ketones
(A) IUPAC Nomeuclatttt'e of Aldehydes and Ketones (B) Synthesis of AldehYdes
[10 I-Iottrsi
(C) Physical Ploperties of Aldehydes
(D) Chemical Properties of Aldehydes (with reaction mechanism) Nucleophilic addition ro >C:O grollp
(E) Synthesis of l(etones
(F) Physical Plopei'ties of Ketones
(G) Chemicai Properties of Ketones (reaction mechanism) Nr-rcleophilic addition tri
>f:g
group
2. Carboxylic Acid and its derivatives
(A) Nomenclature of mono and dicarboxylic
acids
(B) Synthesis of monocarboxylic acids
(C) Physical Properties of mono carboxylic acids
(D) Acidity of Carboxylic acids (E) Effect of substitution on Acidity of carboxylic acids (F) Chemical Properties of tnono carboxylic acids
(G) Reaction of acid Derivatives (H) Mechanism of Esterification
(l) Hydrolysis of Esters (Bxc2 Mechanism) (J) Tlans- estelifi cation
Unit l.
III : Phvsical
Chemistrv
Basic of some physical
properties
2. Phase Rule and related theorl' of
sYstem
lead (Pb-Ag)
solutions
[09 fiours]
[11 llc'rrrsj
Unit IV
: Industrial Chenristry
1. Fuels
2. Synthetic drugs and clyes
.i'
Drugs
chlolamphenicol, veronal
*
Dyes
'/
Classification
Congored, Crystal violet, Anthraquinone
Chemistry Practicals Semester
1. Organic Qualitative
III
Analysis
[10 marksJ
[Minimum six bifunctional Organic Compounds shoulcl be given]
Identification of an organic colnpollnci through the functional group a'*lysis and detennination of melting point or boiling point (Bifunctional organic compounds)
2. organic volumetric
Estimation:
[10 marl
fStandard solution to be given]
1. To determine the amount of -CONH2 in the given Acetamide soltrticn
2.
To determine the amount of Phenol / m-cresol in the given soh-rtigp
3. To determine the amount of Aniline
/ p-toh-rdine in the given soluticl
4. To determine tire amount of Ester in the given sorution 5. To determine the amount of Glr.rcose in the given solution 6. To deterrnine the amount of -COOFI in the given carboxylic
3. Gravimetric Estimation (Any Three) 1. Estirnation of Ba
as BaSO,
2. Estirnation of Fe as Fe2O3 3. Estirnation of Ni
as
4. Estimation of Al
as A1,Or
Ni(DMG)2
acrd
[tr5 marks]
SAUR.ASI{TRA UNIVER.SIT'Y o BgcFr - & t
SEMESTER-IV CHEMISTRY [C-101] SYLLABUS BSc
Unit I : Inorganic ChemistrY
1.
Molecular Orbital TheorY.
I{ybridisation.
2.
tlrgiiiiic Metaiic ComPounds.
.. ,(
preparatior1 of Olgano Berylliuni. Olgarto AluntiniLtm and Zaise Salts-
Structure 1
Tri Methyl aluminium (Dimer )'
)
12) (3
)
of
Zaise Salt IPtClz-CzH4 ].
Fenocette.
Unit Il : Organic ChemistrY 1. Hetroc],clic
Compouncls
(a) Stmctgre anci Aromaticity of FLlratl. Thiopirene ancl llvrrole
(b) Preparation of Fttran. Thiophene and pyrole (c) Chemical Properties of l:ttan^ Thiophene ancl pvrrole
r r
Nitration SLrlPhonatioll
[10 Hours]
(d) Str-ucture and Aromaticity of pyricline (e) Basicity of pyridine
(fl Relative basiciry of py'icrine. pyrrore arrcr Aliphatic
amines
(g) Preparation of pyricrine fi'om aceyrene, hantzsch/s method (h) Chemical properries of pyridine
2. Active Methylene Compounrls
[10 FIou:-s]
(a) Definition (b) Keto-enor
ra'tomeris'
in Etrryr acetoacetate
(c) Proof for strttcture of Etiryl acetoacetate I Frankland
- Dr.rppa stucture
ct GeLrrhci.
Structure] (d) Proof for structure of Ethyl acetoacetate I claisen conclensation v'ith reaction mechanism] (e) Physical proper"ties of Ethyi aceroacetate
(f ) Chemical properties of Ethyl acetoacetate Synthesis fi-orn Ethy,l acetoacerate
Unit
III : Physicat
Chemistry
1. Chemical kinetics
'i
First or.cler reaction
[0 Hours]
& it,s characteristics
nrethod
(lil)
N{ehod of half'-life period (V) Integration rnethod
2. 'fhe colloidal state
[10 Hours]
FIy,droltrtr, Reduction, Oricla:ion, E;tchir'ge of soi','ent, controlied condensation, change of physicai state in short. (il) Dispersion methods such as l3;'edig's r:iethod, b;'r Grinding. Peptization in short.
'.
Properties of colloidal sohrtiorls : (l) Opticai propel'ties srich as Tyndall effect. Brownian etf'ect. ColoLrr Zet a
(iI) Electrical
properties such as Electrical Charge, Electrical double layer &
potential, Catapholesis, EIectro-osmosis.
Unit IV : Industrial Chemistry l. Ceramics and Refectories
2. Synthetic Polymers
Chemistrv Practicals Semester IV
1. Inorganic Qualitative Analysis:
[20 Marksj
[Minimum ten Inorganic mixtures shoulcl be given] Qualitative Analysis of an inolgar-ric mixtnre containing four radicals. e::clridinq Pou-', Croa'2, Cr2o7'2, Aso3
2.
Physicochemical
-3,
Asoa
-t,
Bo,
-3
ancl S-2
Exercise
[15 Marlis]
1. To determine the specific reaction rate of the hydrolysis of rnethl'l acctali Ethyl acetate catalyzecl by H* ion at roorl temperatr,tre.
2, To study
the rate of reaction between K2S2O8 and KI.
3. To str-rcly the rate of reaction
between KBrO3 ancl KI.
,/
and H2SOa To cletermine the relative strength of HCl Energy To determine the temperature coefficient ancl
4. 5.
of activation for
the
of activation for
the
hydrolysis of ester at two different temperatures' ancl Energy determine the temperature coefficient
6.
To
1.
reactionbetweenKzSzosandKlattwodifferenttemperatures given organic acid using anirnal Tc determine the rate of aclsorption of the cnarcoal.
8.
DistributionLaw:Tostuclythepartitlonco-efilcientofbenzoicacidbetween the molecular condition of benzene / ketosene ancl hence stucly water ancl
benzoic acid in the solution' acicl between water and chloroform 9. To stgdy the partition co-efficient of acetic
of acetic acid in the solution' and iience stucly the molecular conclit.ion
REFERENCE BOOKS I Sem'
III & IV ] :-
l.Valency&MoiecuiarStructr:rebyCartrr-rell-Fo.,v]es' Manas Cl-iancla' 2. Atomic Structure & Cherlical Bonding Will
6.
L
: J' D' Lee' Consise Inorganic Chemistry by
by Arun Bahl and B'S'BahI hdvanced Organic Chen-ristry
8.TextBookoforganicChemistryforBscstr'rdentsbyB.S.Bahl and Boyd Organic Chemistry by Morrison by Solor-non, John wiley' 10.Fu'cla',rentals of organic chemistry
g.
]].Textbookol.organicClrenristrybyP.L.SoniandH'M.Chawla
and Structure by Chernistry Reactions, Mechanism 12.N{arch,s Aclvancecl Organic Michael B Smith ancl Jerry N{arcir
/- t1'r:
r.sj:"tti*1t'
J:'-r :s
l3.Reaction Mechanisms and Reagents in Organic Chemistry by Crr-lruclc.p Chatwai
l4.Advanced Organic Reaction Mechanism by N. Teu'ari
l5.Organic Chemistry by I.L.Finar 16.A Textbook of physical chemistry K.I(. Sharma, L.K. Sharma
lT.Physical Chemistry by Dr.D.R. Pandit, A.R. Rao and Padke 18.A Textbook of pirysical chemistry by Samuel Glasstone 19.A Textbook of physical chernistry by B.I(. Shalma
20.Industrial instrumentation by Eckrnan . Donald 2l.Shreeve's Chemical
Process
22.Fuel and cornbustion
by Ar-rstin George
by by Sarkar &
2-3.Inadustrial Cheniistry bv B.
P.
I{ Sharma.
Sarnir
