St. Joseph’s College of Arts & Science (Autonomous) St. Joseph’s College Road, Cuddalore – 607001 EPCH808Q – REAGENTS ANDNAMING REACTIONS
Time : 3 hrs
Max Marks :75 SECTION – A (20X1=20) Answer ALL Questions
I. Choose the correct answer 1. The prefixes Z and E Stand for a) Zeigler – Erhard c) Zirco – Estrogen
b) Zwitter - Erythro d) Zusammen – Entgegen
2. How many diastereomers are shown by the following molecule CH3-CH = CH-CH = CH-C2 H5 a) 1 b) 2 c) 3 d) 4 3. Which of the following is not an Electrophile a) NH3 b) Br+ c) H+
d) BF3
4. The Central C-atom of carbene possesses a) Sextet of electron b) Duet of electrons c) Octet of electrons d) None of these 5. The conversion shown below R – CO – N3 R-NH2 is an H O 2 example of a) Hoffmann rearrangement b) Lossen rearrangement c) Beckmann rearrangement d) Curtius rearrangement
~1~
K2/PG2/15/A16 6. In the Beckmann reaction, migrating group is chiral; select the true statement for it a) It will change its configuration while in migration b) It will retain its configuration while in migration c) It can change as well as it can retain its configuration d) There is nothing to do with configuration 7. Wilkson's catalyst is a) Rh Cl (PPh3)3 c) Rh Cl (PPh3)2
b) Rh Cl (PPh2)3 d) Rh Cl (PPh3)4 OAC
h
8. Predict the products of a)
OAC
+2 ACOH
? OAC
b) ACO OAC
c) ACO
OAC
d) OAC
9. Green chemistry eliminates waste a) At the end of the process c) Middle of the process
b) At source d) None of these
10. Which one is not a green solvent? a) Liquid CO2 c) Water
b) Liquid NH3 d) None of these
II. Fill up the blanks 11. In staggered conformation, torsional energy is____________ 12. _____________refers to ions with positive charge on carbon. 13. The conversion of acetophenone to acetanilide is best accomplished by using ___________ 14. Gilman’s reagent is ______________
~2~
K2/PG2/15/A16 15. ____________ technique does not assist in greener synthesis of chemicals. III. Match the following 16. Optically active
- Isocyanate
17. Carbanion
- Paul T. Anastas
18. Curtius rearrangement
- Spiranes
19. -Cleavage
- Wittig rearrangement
20. Green chemistry
- Cyclo butanones SECTION – B (10X2=20) Answer any TEN Questions
21. Draw all possible conformation for disubstituted cyclohexanes - 1Br - 2 – Cl. 22. What is erythro and threo form? 23. How many conformations are possible for trans – decal – 2 – ol? 24. What is neighbouring group participation? 25. What is reactive intermediates? Give one example? 26. Define carbocation.
~3~
K2/PG2/15/A16 27. Complete the following reaction. CH2 - CH2
(i) NaOH
CH2
CO
(ii) HCl
CH2 - CHCl 28. What is favorskii reaction? 29. Write Hoffmann Rearrangement reaction? 30. What is LDA? How is its use in the field of organic chemistry? 31. Complete the following reaction. CH3 – CH = CH2 + H2
RhCl (Ph3p)3
32. What is green chemistry? SECTION- C (5X7=35) Answer any FIVE Questions 33. a) How enantiotopic and diasterotopic faces are named? b) Explain RS nomenclature with an example of allenes & spiranes.
(3)
34. a) Write a short notes on aryne ? b) Discuss Elimination reaction.
(4) (3)
35. a) Explain Oppenaner oxidation with its mechanism. b) Write cope rearrangement reaction.
(4) (3)
(4)
36. a) Explain the reaction and mechanism of Meerwein – Ponndro – Verley (MPV) reduction. (5)
~4~
K2/PG2/15/A16 b) Complete the following reactions? O Cl
NaOCH3
?
(2)
37. a) Complete the following reactions i) ClCH2CH2O COCH3+ (n-Bu)3SnH ii) R – CO – OH + HO – CO – R b) What are dithiane?
? DCC
?
38. a) Give any five uses of Trimethylsilyl iodide in organic synthesis? b) Complete the following reaction nBu3Sn Me2 C - CH – CO – C4H9 ? H CH2 39. a) State principles of green chemistry. b) How microwave method are used in organic synthesis?
to ions with positive charge on carbon. 13. The conversion of acetophenone to acetanilide is best accomplished. by using ______. 14. Gilman's reagent is ...
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