Eur. Phys. J. B 24, 15–21 (2001)

THE EUROPEAN PHYSICAL JOURNAL B EDP Sciences c Societ`

a Italiana di Fisica Springer-Verlag 2001

Magnetism in systems of exchange coupled nanograins N.H. Hai1,2,a , N.M. Dempsey1 , and D. Givord1 1 2

Laboratoire Louis N´eel, CNRS, BP 166, 38042, Grenoble Cedex 9, France Cryogenic Laboratory, National University of Hanoi, 334 Nguyen Trai, Hanoi, Vietnam Received 22 March 2001 and Received in final form 23 July 2001 Abstract. Due to exchange interactions across interfaces, the finite temperature intrinsic magnetic properties (magnetisation, anisotropy) of nanostructured systems differ from those which would be observed in the absence of coupling. These properties are calculated within a simple molecular field approach for classical moment two-component systems, each component being characterised by the value of its Curie temperature, TC , i.e., the strength of exchange. Magnetisation and anisotropy are influenced over a few (≈5–10) interatomic distances. Close to the Curie temperature of the lower-TC ferromagnet the influence is very significant (typically 20–50% for magnetisation and 2–20% for anisotropy). The model is extended to systems in which rare earth (R) – transition metal (T) compounds are coupled to Fe or Co. Analysis of the results suggests that the change of intrinsic magnetic properties through interface exchange coupling will not induce a significant coercivity. PACS. 75.70.Cn Interfacial magnetic properties (multilayers, superlattices) – 75.30.-m Intrinsic properties of magnetically ordered materials – 75.50.Ww Permanent magnets

1 Introduction Nanostructured systems, such as exchange coupled spring magnets [1] or ultra soft FeBSiCu alloys [2], which consist of an intimate mixture of grains with distinct magnetic properties (magnetisation, Curie temperature, anisotropy), have been the subject of many recent studies. Experimental studies, supported by numerical simulations, show that the magnetisation processes in these systems differ from those which would result from a simple addition of the grains individual properties. This behaviour results from exchange coupling existing between grains. In the same way as it affects the magnetisation processes, which are determined by the material’s extrinsic magnetic properties, exchange coupling should modify the material’s intrinsic magnetic properties, in particular the temperature dependence of the magnetisation and that of the anisotropy. This has been considered for antiferromagnetic superlattices by Wang and Mills [3] and by Carri¸co and Camley [4]. However these authors did not present details of the calculation of the magnetic properties. Additionally, to our knowledge, the case of nanostructured ferromagnetic systems has not been examined. A simple 1D model is presented and the extrapolation to 3D is described. The temperature dependence of magnetisation and anisotropy in systems of classical moments are calculated. An extension to R-T alloys, in which large 3D interactions due to the T moments and large anisotropies due to the R moments coexist, is presented. a

e-mail: [email protected]

2 1D modelling of coupling between nanograins 2.1 Molecular field modelling of a heterogeneous system The static properties of a magnetic system in the ordered state can be well described within the molecular field approach. The molecular field Bi acting on atom i is expressed as: X Bi = nij hµj iT (1) j

where nij is the molecular field coefficient, hµj iT is the thermal average of µj , at temperature T , and the summation extends over all other atoms, j. Assuming that interactions exist between first nearest neighbours only, relation (1) becomes: Bi =

j=Z X

nij hµj iT

(2)

j=1

where the summation is restricted to the Z first nearest neighbours of atom i. In this section where a 1D model is developed, atoms are assumed to form a stacking of 2N +1 planes, the overall structure being symmetric about a central plane denoted 0 (Fig. 1a). Atoms in plane i have z0 neighbours in their own plane, z− neighbours in plane i − 1 and z+ neighbours in

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where nint is the molecular field coefficient between nearest neighbour atoms located on opposite sides of the interface. Similarly, in plane I + 1, the molecular field is: (int)

BI+1 = n(int) z− hµI iT + n(II) z0 hµI+1 iT + n(II) z+ hµI+2 iT . (3d)

(a)

Finally, we take the entire sample to consist of a repeat stacking of identical bilayers of material (I) and (II) so that plane N may be assumed to be next to plane −N . To this set of 2N + 1 equations, which expresses the molecular field as a function of the magnetic moments, another set of equations is associated which expresses the moments as a function of the molecular field. Assuming classical moments, this is: hµi iT = L (xi )

(4)

where L (xi ) is the Langevin function, xi = µi (0)Bi /k T and i runs from −N to N . 2.2 Magnetisation

(b) Fig. 1. Schematic diagram of the model nanocomposite systems comprising two distinct materials, (I) and (II), considered for (a) 1D calculations and (b) 3D calculations. The relative sizes of the components are characterised by the number of atomic planes, I and J for material (I) and (II), respectively.

plane i + 1 (z0 + z− + z+ = Z, the total number of nearest neighbour atoms). To model the heterogeneous nature of matter, which is our precise interest, atoms from i = 0 to I are assumed to belong to material (I), while atoms from i = I + 1 to N (N − I is defined as J) are assumed to belong to material (II). In addition, it is assumed that, within a given material, interactions with all neighbours are identical, i.e., nij = n(I) within (I) and nij = n(II) within (II). Within (I), the molecular field is expressed as: (I)

Bi

= n(I) z− hµi−1 iT + n(I) z0 hµi iT + n(I) z+ hµi+1 iT (3a)

and within (II), it is expressed as: (II)

Bi

= n(II) z− hµi−1 iT + n(II) z0 hµi iT + n(II) z+ hµi+1 iT . (3b)

The molecular field in plane I at the interface is: (int)

BI

= n(I) z− hµI−1 iT + n(I) z0 hµI iT + n(int) z+ hµI+1 iT (3c)

The hµi iT ’s and Bi ’s can be calculated self-consistently from the above 2 sets of equations, thus allowing the moment configuration to be deduced. For numerical calculations, the hµi iT ’s were expressed in terms of the zero temperature moment µ(0) which was assumed to be the same in both materials (I) and (II). The Curie tempera(II) ture in (II), TC , was taken as a reference (n is related to TC through Z nµ(0)2 = 3 k TC where the effective moment, µeff , is identical to µ(0) for a system of classical moments). z0 = 2 z− = 2 z+ was assumed (for an fcc system, along [111], z0 = 6, z− = z+ = 3). Calculations were (I) performed for various values of the four parameters: TC , I, n(int) and T (five layers of the high TC phase are considered, i.e., J = 5). Initially, all moments were assumed to be equal and saturated. This provides initial values for the Bi ’s (Eq. (3)) from which the µi ’s are extracted (Eq. (4)). The molecular field in each plane is then recalculated and the procedure is repeated until ∆µi /µi < 10−8 where ∆µi is the difference between two consecutive values of µi . (I) The magnetisation profile at T = TC is shown in Fig(I) (II) ure 2a, for a system characterised by TC = (1/2)TC , I = 5 and n(int) = (n(I) + n(II) )/2 (i.e., n(int) is simply taken as the average between n(I) and n(II) ). The moment configuration is compared to the configuration which would be obtained in the absence of coupling between (I) and (II) when n(int) = 0 (note that in this case, the moments in (II) next to the interface have reduced values with respect to the bulk value due to the lower number of neighbouring moments). The additional interactions resulting from coupling across the interface lead to a significant induced magnetisation in (I) and a small increase in the magnetisation in (II). The latter observation justifies the fact that we consider just five layers in the high TC material. The induced magnetisation in (I) occurs up to the centre even though coupling only exists between first

N.H. Hai et al.: Magnetism in systems of exchange coupled nanograins

µ i (Τ)/µ(0)

17

Tc(I)

(a)

Tc(II)

Temperature (a.u.)

µ i (Τ)/µ(0)

(a)

(b) Fig. 2. Magnetisation profiles at the interface between mate(I) (II) rial (I) and material (II) at temperature T = TC = 0.5 TC for (a) I = 5 and (b) I = 20 (the number of planes in (I) is 2I + 1). Symbols: ∇: n(int) = 0 (no coupling), 1D calculation; ×: n(int) = 0, 3D calculation; ◦: n(int) = (n(I) + n(II) )/2, 1D calculation; : n(int) = (n(I) + n(II) )/2, 3D calculation.

nearest-neighbours. For I = 20 (Fig. 2b), the polarisation is still significant at the centre of (I), but the larger the value of I, the lower the polarisation at the centre. Actually, comparison of Figures 2a and 2b shows that it is more significant to consider the distance of a given plane from the interface. The polarisation decreases with distance from the interface, amounting to about 0.2 Ms at the fifth plane. The temperature dependence of the reduced magnetisation mi (T ) = µi (T )/µi (0) in different planes i, within (I) and (II) is compared in Figure 3a to the temperature dependence of the bulk reduced magnetisation mb (T ) (assumed to be described by the Langevin function L(xi ) (I) with µi (0) = µ(0) and Bi = 3kTC /µ(0) in phase (I) (II) and Bi = 3kTC /µ(0) in phase (II)) in both materials for I = 20 and n(int) = (n(I) + n(II) )/2. The dif-

Tc(I)

Tc(II)

Temperature (a.u.)

(b) Fig. 3. Temperature dependence of the reduced magnetisation mi (T ) = µi (T )/µi (0) in different planes within (I) and (II) compared to the temperature dependence of the reduced magnetisation in the bulk (a) I = 20, n(int) = (n(I) + n(II) )/2 and (b) I = 20, n(int) = (n(I) + n(II) )/10. The planes are labelled i ≤ 20 in the low TC material and i > 20 in the high TC material (as not all planes are individually marked, an arrow indicating the direction of increasing i is included).

ference with bulk behaviour becomes progressively more significant as temperature is increased, the effect being greater for planes close to the interface. This behaviour is a consequence of the fact that the temperature dependence of the magnetisation is directly related to the strength of exchange interactions while the 0 K magnetisation itself does not depend on the strength of the interactions (see Eq. (3)). The temperature dependence

The European Physical Journal B

2

2

was also evaluated for a lower assumed value of interface coupling (n(int) = (n(I) + n(II) )/10) (Fig. 3b). Close to the interface, the magnetisation at relatively low temperature is reduced with respect to the bulk value due to the reduction in exchange coupling. Inversely, an induced magnetisation persists in (I) (although 2–3 times (I) less than for n(int) = (n(I) + n(II) )/2) at T > TC due to coupling with (II). As a result of the qualitatively different behaviours at low and high temperatures respectively, the temperature dependence of the magnetisation in any given plane of (I) crosses that of the bulk at a cer(I) tain temperature below TC . For n(int) = (n(I) + n(II) )/10, (I) this temperature is about 0.95 TC . As n(int) increases up to n(I) , the crossing temperature decreases down to 0 K. For n(int) > n(I) , there is no crossing since the magnetisation in all planes of (I) is higher than in the bulk. This is the case for n(int) = (n(I) + n(II) )/2, in Figure 3a.

K (T)/K (0)

18

Tc(I)

Tc(II)

Temperature (a.u.)

(a)

Kn,i(T ) = Kn,i (0) fn [µi (T )/µ0 ],

n(n+1)/2

4

(5)

where Kn,i (0) is the anisotropy at 0 K and fn is a function which depends on n and has been calculated by Callen and Callen [5] (to first order, fn (µi (T )/µ0 ) ≈ (µi (T )/µ0 )n(n+1)/2 , the Akulov law [6]). The temperature dependence of the reduced anisotropy constants kn,i (T ) = Kn,i (T )/Kn,i(0) (n = 2 and n = 4), deduced from the fn calculated by Callen and Callen, are plotted in Figures 4a and 4b respectively (n(int) = (n(I) + n(II) )/2). To first approximation, the ratio of anisotropies in two different planes at temperature T is: Kn,i (T )/Kn,i+1 (T ) = [µi (T )/µi+1 (T )]

4

In such systems of classical moments, the decrease of anisotropy with temperature is only determined by thermally activated fluctuations of the moment orientations [5]. It can thus be expected that the anisotropy value is affected at the interface between (I) and (II), in a similar way to which the magnetisation value is affected. The anisotropy constant of order n, characterising atoms in plane i at temperature T , is Kn,i (T ) and may be written as:

K (T)/K (0)

2.3 Anisotropy

(6)

i.e., the relative variation of anisotropy from one plane to the next is much more abrupt than the variation of (I) magnetisation. Thus at T = TC , the 2nd order anisotropy in the fifth plane from the interface within (I) amounts to 0.025 K2,b, where K2,b is the 0 K bulk 2nd order constant, while the magnetisation is only reduced to 0.2 Ms . At the same temperature, the 4th order anisotropy in the same fifth plane amounts to 0.01 K4,b.

3 3D modelling of coupling between nanograins A simple extension of the above calculations to 3D is obtained by assuming that the atoms are distributed within

Tc(I)

Tc(II)

Temperature (a.u.)

(b) Fig. 4. Temperature dependence of the reduced anisotropy constants kn,i (T ) for n(int) = (n(I) + n(II) )/2, (a) n = 2 and (b) n = 4. The planes are labelled i ≤ 20 in the low TC material and i > 20 in the high TC material (as not all planes are individually marked, an arrow indicating the direction of increasing i is included). Planes i = 0−18 and i = 22−25 are indistinguishable from the bulk profiles.

successive spherical shells (Fig. 1b). The total sphere radius is N . The outer part, for radii ranging from I + 1 to N , consists of the high-TC material (II), the core is a sphere of radius I and consists of the low-TC material (I). The number of atoms contained within the ith shell is 3 i2 (d/rat )3 , where d is the distance between the centres of √ neighbouring shells and rat is the atomic radius. (d/rat ) = 2/3 was assumed, which corresponds to the d value between atomic planes along the [111] direction of a cubic fcc material. The parameters z0 , z− and z+ within a given shell were taken to be proportional to the number

N.H. Hai et al.: Magnetism in systems of exchange coupled nanograins

19

Table 1. Magnetic parameters used for modelling the coupling between rare earth – transition metal nanograins.

–2.2 [8]

–3.0 [9]

0.085 [7]

0.119 [8]

–0.0076 [9]

B60 (K)

0 [7]

0.001 [8]

–0.008 [9]

of atoms within this shell with the additional condition that Z = 12 whatever the value of i. z− and z+ tend to 3 and z0 tends to 6 as N tends to infinity. The same type of calculations as for 1D were performed. Since z0 , z− and z+ are now dependent on i, the cyclic boundary conditions no longer apply. A 3D magnetisation profile is compared to the 1D profile for consistent parameter values in Figures 2a and 2b. The results are qualitatively similar. Actually, 1D and 3D calculations differ only in the number of atoms in neighbouring planes. In 3D, the number of atoms per shell increases when moving out from the centre of the sphere. Thus the atoms in the last shell of material (I) have a greater number of neighbours in the outer shell which belongs to the highTC material (II) than in the inner shell which belongs to low-TC material (I). It results that the polarisation in 3D is enhanced with respect to the polarisation in 1D.

n n,i

– 8.0 [7]

B40 (K)

Temperature (K)

(a)

n

B20 (K)

n,i

565 10.51 [9]

µ i (Τ)/µ(0)

592 8.67 [8]

K

997 20 [7]

(T)/K (0)

TC (K) nRT (K/µ2B )

(T)/K (0)

Pr2 Fe14 B

µ i (Τ)/µ(0)

Nd2 Fe14 B

K

SmCo5

4 Modelling the coupling between rare earth-transition metal nanograins

Temperature (K)

n,i

n

(T)/K (0) K

µ i (Τ)/µ(0)

(b)

High coercivity (SmCo5 , Nd2 Fe14 B, etc.) or high magnetostriction (RFe2 ) magnetic materials are based on rare earth – transition metal compounds. Magnetic ordering is mainly determined by large T-T exchange interactions whereas the anisotropy results from the coupling of the anisotropic R 4f shell with the environment. Modelling the behaviour of nanosystems including such R-T compounds is discussed in this section. Three systems were considered, namely SmCo5 /Co, Nd2 Fe14 B/Fe, and Pr2 Fe14 B/Fe. The magnetic properties of the considered compounds, relevant to the present discussion (Curie temperature TC , crystal field parameters Bn,m ) are given in Table 1. 3D calculations only are reported here. Within the Fe or Co region, as well as within the R-T region, calculation of the T magnetisation is essentially identical to calculations performed in the above sections. The temperature dependence of the reduced magnetisation mT i (T) (T = Fe or Co) is presented in Figure 5 for I = 20 and n(int) = (n(I) + n(II) )/2 (bulk behaviour also shown). The results are qualitatively similar to those obtained in the previous sections and presented in Figure 3a. However they are quantitatively different because (I) (II) the Curie temperatures TC and TC are not in the exact ratio of 1 : 2.

Temperature (K)

(c) Fig. 5. Temperature dependence of mTi (T ) (T = Fe or Co), mR i (T ) (R = rare earth), and the anisotropy constants RT (T ) (I = 20 and n(int) = (n(I) + n(II) )/2) (a) SmCo5 /Co, kn,i (b) Nd2 Fe14 B/Fe and (c) Pr2 Fe14 B/Fe. The planes are labelled i ≤ 20 in the low TC material (mT and mR ) and i > 20 in the high TC material (mT only) (as not all planes are individually marked, an arrow indicating the direction of increasing i is included).

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The European Physical Journal B

The R magnetic state at a given temperature T is defined in principle by R-T and R-R exchange interactions as well as by Crystalline Electric Field interactions. Of all these terms however, the R-T interactions are dominant. Neglecting the other terms, the thermal average of gJ µB Jz , which defines the magnetisation, is deduced by assuming that the separation between each level of the J multiplet is the same, and equal to gJ µB Bex,i where gJ is the Land´e factor for the considered R element, µB is the Bohr magneton and Bex,i = nRT hµT,i iT , where nRT is the molecular field coefficient describing the coupling between the R and T moments (see Tab. 1). The R moment is then given by the Brillouin function BJ (xi ) where the quantum number J characterises a given R element and xi is given by: xi = gJ µB JBex,i /kT.

(7)

The calculated temperature dependence of mR i (T ) for the 3 systems considered is presented in Figure 5. In all R cases, mR i (T ) is higher than the bulk mb (T ), R-T exchange interactions being enhanced as a result of the coupling between the R-T compound (low-TC material (I)) on one side and Fe or Co metal (high-TC material (II)) on the other side. However the decrease of the R magnetisation with increasing temperature becomes significant in R-T compounds at lower temperature than that of the T magnetisation. Thus, at a given finite temperature, the polarisability of the R magnetisation is less than that of the T magnetisation. This explains why the effect of the interface exchange coupling in Figure 5 is much less spectacular for the R magnetisation than it is for the T magnetisation. Let us now turn to the evaluation of anisotropy. In the present systems, the Fe or Co anisotropy is negligible with respect to the SmCo5 , Nd2 Fe14 B, or Pr2 Fe14 B anisotropy and thus only the rare-earth compound anisotropy was considered. It is the combination of a significant T anisotropy and a dominant R anisotropy. The T anisotropy was taken from literature [10,11]. The R anisotropy is related to the hOn,m,i iT ’s , i.e., the thermal averages of the Stevens operators: K2R = −1/2 3κ02 + 10κ04 + 21κ06  K4R = 1/8 35κ04 + 189κ06 K6R

=

−231/6κ06



(8a) (8b) (8c)

where κ0n = Bn0 hOn0 iT . The hOn,m,i iT ’s were calculated following the same procedure used to evaluate the R magnetisation. The resulting temperature dependence of RT the reduced anisotropy constants kn,i (T ) in SmCo5 /Co, Nd2 Fe14 B/Fe, and Pr2 Fe14 B/Fe nanosystems are shown in Figure 5. The same qualitative relationship as observed above between mi and kn,i (Sects. 2.2 and 2.3) exists beRT tween mR i and kn,i . This, combined with the fact that the R magnetisation polarisability is weaker than the T magnetisation polarisability, explains why the absolute induced anisotropy is almost negligible (Fig. 5).

5 Discussion and conclusion We have developed a simple model, based on the mean field approach, to calculate the change in the intrinsic magnetic properties of two different materials, with different Curie temperatures, intimately mixed on the nanometre scale (i.e., nanocomposite systems). As we are concerned with mixed transition metal and rare-earth transition-metal systems, we consider nearest neighbour interactions only, supposing that RKKY interactions are negligible. Though our results are not surprising, indeed the qualitative behaviour observed is intuitive, our simple model allows an approximation of the length scales over which the modification of intrinsic properties due to exchange interactions is significant in nanocomposite systems. The calculated temperature dependence of the magnetisation in material (I) of the present study (low TC material) is characterised by an inflexion point occurring at (I) a temperature which is slightly higher than TC . Such a behaviour results from the fact that the moments in (I) are weakly coupled between themselves as well as with the moments in (II). The same behaviour characterises the temperature dependence of the magnetisation at the R sites in rare-earth iron garnets and R-T compounds, when the exchange interactions at the R sites are reduced. There is much experimental evidence for the influence of exchange coupling on the extrinsic magnetic properties of nanocomposite materials and the consequential influence on intrinsic magnetic properties has been evoked. In a recent study on Nd2 Fe14 B/α-Fe nanocomposite materials, Lewis and Panchanathan have reported an increase in the Curie temperature of the hard constituents from approximately 575 K to 590–600 K [12]. They have suggested that this increase is due to either exchange coupling of the Nd2 Fe14 B grains with the Fe grains, or to internal stresses. However, our calculations show that the modification of the magnetisation of the low TC material is significant over just 5 to 10 interatomic distances, which is very much shorter than the grain size of the low TC constituent in these systems (25–50 nm). Moreover, due to the coupling between all moments, it is impossible to define separate Curie temperatures for the different materials in these systems. The actual Curie temperature, at which the magnetisation at all sites vanishes, is close to, but less than, TC (II) (see Fig. 3). In conclusion, at finite temperature, the intrinsic magnetic properties of the constituent materials in nanostructured systems differ from bulk properties. This is due to exchange coupling through interfaces. As a general rule, the magnetisation is relatively more affected than the anisotropy. At the interface between two simple ferromagnets with Curie temperatures in the ratio 1 : 2 (for instance this approximately corresponds to Nd2 Fe14 B : Fe metal), an induced magnetisation which amounts to up to 50% of the 0 K value may be observed at the Curie temperature of the low TC material. In R-T compounds, the induced magnetisation and anisotropies at the T sites are higher than those at the R sites. The induced interface R magnetisation calculated for known hard magnetic materials (SmCo5 , R2 Fe14 B) never exceeds 20% of the 0 K value

N.H. Hai et al.: Magnetism in systems of exchange coupled nanograins

and the R induced anisotropy is less than 1%. The modification of intrinsic magnetic properties should in turn influence magnetisation processes. These effects should be greater in systems where the domain wall width, which defines the activation volume in which reversal is initiated, is of the order of a few interatomic distances, and thus corresponds to the distance over which intrinsic magnetic properties are affected by coupling. Such domain wall widths are, at room temperature, characteristic of T-rich R-T compounds. At this temperature, exchange energy and anisotropy are not significantly affected by coupling. At higher temperature when the induced magnetisation becomes significant, the anisotropy is very weak. Thus, the change of intrinsic magnetic properties due to interface exchange coupling should not dramatically affect magnetisation reversal processes.

This work was carried out within the framework of the European project HITEMAG (GRD1-1999-11125) which is supported by the Commission of the European Union (D.G. XII). N.H. Hai gratefully acknowledges support of the CNRS–PICS programme (Nanomateriaux) and the French Embassy in Vietnam.

21

References 1. E. Kneller, R. Hawig, I.E.E.E. Trans. Mag. 27, 3588 (1991). 2. Y. Yoshizawa, S. Oguma, K. Yamauchi, J. Appl. Phys. 64, 6044 (1988). 3. R.W. Wang, D.L. Mills, Phys. Rev. B 46, 1168 (1992). 4. A.S. Carri¸co, R.E. Camley, Sol. Stat. Commun. 82, 161 (1992). 5. H.B. Callen, E. Callen, J. Phys. Chem. Solids. 27, 1271 (1966). 6. N. Akulov, Z. Phys. 100, 197 (1936). 7. D. Givord, J. Laforest, J. Schweizer, F. Tasset, J. Appl. Phys. 50, 2008 (1979). 8. J.M. Cadogan, J.P. Gavigan, D. Givord, H.S. Li, J. Phys. F 18, 779 (1988). 9. J.P. Gavigan, H.S. Li, J.M.D. Coey, J.M. Cadogan, D. Givord, J. Phys. F 49, 779 (1988). 10. J.M. Alameda, D. Givord, R. Lemaire, Q. Lu, J. Appl. Phys. 52, 2079 (1981). 11. D. Givord, H.S. Li, R. Perrier de la Bˆ athie, Sol. Stat. Commun. 51, 857 (1984). 12. L.H. Lewis, V. Panchanathan, Proceedings of the Fifteenth International Workshop on Rare-Earth Magnets and their Applications, Dresden (1998) Germany, Vol. 1, edited by L. Schultz, K.-H. M¨ uller (WerkstoffInformationgesellschaft, Frankfurt, 1998), p. 233.

Magnetism in systems of exchange coupled nanograins - Springer Link

Societ`a Italiana di Fisica. Springer-Verlag 2001. Magnetism in systems of exchange coupled nanograins. N.H. Hai1,2,a, N.M. Dempsey1, and D. Givord1.

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Mar 16, 2011 - in multivariate distributions, and introduce some coefficients to measure that depen- dence. ... and C(u) = uk whenever all coordinates of u are 1 except maybe uk; and. (ii) for every a = (a1, a2,..., ...... IMS Lecture Notes-Mono-.

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Nov 10, 2005 - species, detection of drug resistance, and typing for epi- demiological investigation. In the laboratory diagnosis of tuberculosis, the nucleic acid ...

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improvement criteria (Madden 1986). Some see distributional problems as reason to reject utilitarianism entirely (Machan 1984; Dworkin I977). Each of these.

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sic characteristic of life, although it can be lost when their costs are higher than their ... individuals with visceral regeneration in progress [7, 25–28], indicates that the ... In the following stages, the regrowth of the intestinal tract can i

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projected by measuring the node degree, betweenness and closeness for each node within these networks. Additionally, promiscuity maps and heat maps were.

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represent stations with storage capabilities, while the edges of the graph represent com- ... message time-delays along a path in a communication network.

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Oct 10, 2008 - Springer Science + Business Media, LLC 2008. Abstract We .... In addition to Procolobus kirkii, Zanzibar Island supports endemic and near-.