USO0RE43969E

(19) United States (12) Reissued Patent

(10) Patent Number: US RE43,969 E (45) Date of Reissued Patent: *Feb. 5, 2013

Kobayashi et a]. (54)

INFORMATION RECORDING MEDIUM AND

(56)

METHOD OF MANUFACTURING RESINOUS SUBSTRATE FOR USE IN THE RECORDING MEDIUM

References Cited U.S. PATENT DOCUMENTS 5,126,996 A

6/1992 Iida et al.

(Continued) (75) Inventors: Tadashi Kobayashi, Chiba (JP); Hisashi

Yamada, Yokohama (JP) (73) Assignee: Kabushiki Kaisha Toshiba, KaWasaki-shi (JP) (*)

Notice:

(21) Appl.No.: 12/476,449

8/1989 1/1991

OTHER PUBLICATIONS

Blu-ray Disc “Recordable Format, Part 1 Physical Speci?cations”, Feb. 2006.

(Continued)

Jun. 2, 2009

Primary Examiner * Elizabeth Mulvaney (74) Attorney, Agent, or Firm * Oblon,

Related US. Patent Documents

Reissue of:

Spivak,

McClelland, Maier & Neustadt, L.L.P.

(64) Patent No.: Issued:

Appl. No.: Filed: US. Applications:

6,465,069 Oct. 15, 2002

(57)

09/657,566 Sep. 8, 2000

An information recording medium comprising a substrate having a recording surface provided With emboss pits or guiding grooves, a re?ective ?lm formed on the recording surface of the substrate, and a ?rst protective ?lm formed on the re?ective ?lm. This information recording medium is featured in that both sides of the information recording medium are constituted by a ?rst surface provided With the protective ?lm and by a second surface formed opposite to the ?rst surface, and that an irradiated light beam is irradiated through the ?rst surface, a recorded information being repro duced based on changes in light intensity of the re?ected light beam. The distance between the recording surface of the substrate and the light incident surface is smaller than a thick ness of the substrate, and a surface roughness “R” of the light incident surface meets a relationship represented by the fol

(62)

Division of application No. 12/028,491, ?led on Feb. 8, 2008, Which is a division of application No. 09/283, 161, ?led on Apr. 1, 1999, noW Pat. No. 6,159,572.

(30)

Foreign Application Priority Data Apr. 3, 1998

(JP) ................................... .. 10-091422

(51)

Int. Cl. B32B 3/02

(52)

US. Cl. ................... .. 428/64.1; 428/64.4; 428/64.5;

(2006.01)

428/64.6; 428/457; 430/270.12; 430/270.13; 430/495.1; 369/275.1; 369/283; 369/288 (58)

01-211251 3-008153

(Continued)

This patent is subject to a terminal dis claimer.

(22) Filed:

FOREIGN PATENT DOCUMENTS JP JP

Field of Classi?cation Search ............... .. 428/64.1;

430/270.11

See application ?le for complete search history.

/

ABSTRACT

loWing formula (1): Rik/(8n) (1) Wherein 7» is a Wavelength of the light beam, and n is a refractive index of the ?rst protective ?lm to a light

having the Wavelength 7». 1 Claim, 10 Drawing Sheets

US RE43,969 E Page 2 US. PATENT DOCUMENTS

JP

8-235638

9/1996

5,476,700 A * 12/1995 Asai et a1. .................. .. 428/666

5;

02334633

$1332

5,604,003 A

2/1997 Coombs

JP

8639573

l2/1996

5,640,382 A *

6/1997 FlorcZak et al. ......... .. 369/275.1

JP

09447417

6/l997

JP JP JP JP

09461334 9_204686 9_204688 9_274736

6/1997 8/1997 8/1997 l0/l997

5,673,251 5,702,792 5,757,733 5,764,619

A A A A

5,766,717 A *

5,907,534 A 5,972,459 A 5,972,461 A 6,023,451 A *

6,159,572 A 6’246’656 Bl *

9/1997 12/1997 5/1998 6/1998 6/1998

Suzuki et al. Lida Gardner et a1. Nishiuchi et al. Kaneko 6t ill. ............. ..

5/1999 Yamatsu 10/1999 Kawakubo 10/1999 Sandstrom

JP

09_288846

11/1997

JP JP JP

09620115 10-083571 10.326435

12/1997 3/199g 12/199g

2/2000 Kashiwagi et a1. ...... .. 369/275.5

12/2000 Kobayashi 6/2001 Kawakubo et a1‘ "" " 369/1023

FOREIGN PATENT DOCUMENTS

JP

05420731

5/1993

JP

06-076372

3/1994

JP

07487868

10/1995

JP

8.124216

5/1996

JP

8-221802

8/1996

JP

08-221802

8/1996

OTHER PUBLICATIONS Blu-ray Disc “1.C Physical Format Speci?ction for BD-ROM”, 5th Edition, Mal 2007~ _

éeggaérgzse Of?ce Action dated Jun. 16, 2009 for Appln. No. 2005 '

Of?ce Action issued Dec‘. 7, 2010, in Japan Patent Application No. 2006-196020 (with English-language Translation). * cited by examiner

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US RE43,969 E 1

2

INFORMATION RECORDING MEDIUM AND METHOD OF MANUFACTURING RESINOUS SUBSTRATE FOR USE IN THE RECORDING MEDIUM

singly. Therefore, in order to prevent the substrate from being warped, a couple of PC substrates each having a thickness of 0.6 mm are superimposed each other with the recording sur

face being directed inside, thus forming a disk having a total thickness of 1.2 mm, thereby ensuring the mechanical prop erty thereof.

Matter enclosed in heavy brackets [ ] appears in the original patent but forms no part of this reissue speci?ca

The reason for setting the substrate of DVD to 0.6 mm is to

secure the tilt margin of the disk. When the density of track pitch or pit is increased, the margin of the inclination or so-called tilt of the disk is caused to decrease. Although it may be possible to secure the tilt margin by decreasing the thick

tion; matter printed in italics indicates the additions made by reissue.

ness of the substrate from 1.2 mm to 0.6 mm, it will inevitably result in a deterioration of the mechanical property thereof. Under the circumstances, there has been proposed, with a view to secure the mechanical strength of the disk while decreasing the thickness of the substrate, an idea of thicken

This application is a [division] divisional reissue applica tion of US. application Ser. No. 12/028,491, ?led Feb. 8, 2008. US. application Ser. No. 12/028, 491 is a reissue appli

cation of US. application Ser. No. 09/657,566, filed Sep. 8, 2000, now US. Pat. No. 6,465,069. US. Pat. No. 6,465,069 is

ing the central portion of the disk thereby to ensure the

a divisional of [Application] US. application Ser. No.

09/283,161, ?led Apr. 1, 1999[. Allowed as], now US. Pat. No. 6,159,572 andfor which priority is claimed under 35 U.S.C. §121 and 35 U.S.C. §251. This application is based upon and claims the benefit ofpriority under 35 US. C. §119 from the prior Japanese Patent Application No. 10-091422, ?ledApr 3, 1998. Notice: More than one reissue application has been?ledfor the reissue ofU.S. Pat. No. 6,465,069. The reissue applications are application Ser. Nos. 12/476,449,

20

a su?icient mechanical strength, to make the thickness of the

signal recording region of the substrate at least 0.6 mm. Further, there is also reported an idea of making the thickness of the substrate to range from 0.1 mm to 0.6 mm (Japanese 25

12/476,441, 12/476,434, 12/476,428, 12/476,375, 12/476, 456, 12/476,607, 12/476,627, 12/476,685, 12/476,703, and

?lm as well as the ?lm thickness of the re?ective ?lm are not

actual application thereof. 30

beam incident side, and a ?at substrate sustaining a recording ?lm. However, this covering layer is simply referred to as 35

employed for the information recording medium. In particu

having a thickness of 0.6 to 1.0 mm.

For the purpose of further increasing the capacity of the

disk by compacting the recording density, it is more effective,

lar, this invention relates to a surface recording/reproducing type information recording medium and to a method of manu facturing a resinous substrate to be employed for such an

information recording medium.

US. Pat. No. 5,757,733 teaches an information recording

medium comprising a covering layer formed on the light

BACKGROUND OF THE INVENTION This invention relates to an information recording medium and to a method of manufacturing a resinous substrate to be

Patent Unexamined Publication H9-204688). However, the thickness of a protective substrate for sustaining the recording referred to in the idea, thus making it di?icult to practice in the

12/476, 745, all of which are divisional reissues of reissue

application Ser. No. 12/028,491.

mechanical strength thereof (Japanese Patent Unexamined Publication H9-204686). However, it is required, for ensuring

in view of assuring the tilt margin, to make the thickness of the 40

An ordinary optical disk such as CD, CD-ROM, etc. is constructed such that emboss pits are formed in conformity

substrate as thin as possible. However, when the thickness of the substrate becomes less than 0.6 mm, it becomes di?icult to secure the mechanical strength thereof even if a couple of substrates are superimposed each other.

with the recorded data on one of the surfaces of a transparent

Moreover, this superimposition of a couple of substrates is

substrate having a thickness of 1.2 mm, the emboss pits being covered thereon by a re?ective ?lm made of Al for example.

accompanied with the problems that it not only requires the 45

The information recorded in the CD constructed in this man ner can be reproduced by irradiating a converging beam onto

the emboss pits from a surface of the transparent substrate which is opposite to the other surface where the re?ective ?lm is formed. On the other hand, an optical disk such as DVD, DVD ROM where the recording density is highly enhanced is con structed such that ?ner emboss pits than those of the CD are

BRIEF SUMMARY OF THE INVENTION 50

strength even if the recording density is further increased. Another object of the present invention is to provide a 55

generally employed. This PC substrate having a thickness of

method of manufacturing a resinous substrate which is

adapted to be employed for such an information recording medium.

constructed in this manner can be reproduced in the same

manner as that of the CD, i.e. by irradiating a converging beam onto the emboss pits from a surface of the transparent substrate which is opposite to the other surface where the re?ective ?lm is formed. As for the material for the substrate having a thickness of 0.6 mm, PC (polycarbonate) which is a transparent resin is

Therefore, the object of the present invention is to provide an information recording medium which is capable of secur ing a su?icient tilt margin and a su?icient mechanical

formed on one of the surfaces of a transparent substrate hav

ing a thickness of 0.6 mm, the emboss pits being also covered thereon by a re?ective ?lm made of Al for example. The information recorded on the recording surface of the disk

employment of an adhesive but also makes the manufacturing process thereof more complicated.

60

Namely, according to this invention, there is provided an information recording medium, which comprises a substrate having a recording surface provided with emboss pits or guiding grooves; a re?ective ?lm formed on the recording surface of the substrate; and a ?rst protective ?lm formed on

the re?ective ?lm; wherein both sides of the information recording medium

0.6 mm however is not suf?cient in mechanical property,

are constituted by a ?rst surface constituting an upper most surface on the ?rst protective ?lm and by a second

resulting in the warping of the substrate as it is employed

surface formed opposite to the ?rst surface;

65

US RE43,969 E 4

3

a light beam to be irradiated is designed to be entered and

the ?rst surface is constituted as a light incident surface, thereby allowing an irradiated light beam to enter and re?ect through the ?rst surface, a recorded information

being reproduced based on changes in light intensity of the re?ected light beam; and Wherein

5

a distance betWeen the recording surface of the substrate and the light incident surface is smaller than a thick ness of the substrate, and a surface roughness “R” of the light incident surface meets a relationship repre

re?ected through the light incident surface, a recorded information being reproduced based on changes in light intensity of the re?ected light beam. Further, this invention also provides a method of manufac turing a resinous substrate having a ?rst recording surface provided With emboss pits or guiding grooves, and a second recording surface facing the ?rst recording surface and pro vided With emboss pits or guiding grooves, Which comprises

the steps of;

sented by the folloWing formula (1):

mounting a ?rst stamper platen for forming a ?rst record ing surface on a ?rst die;

Rik/(8n) (1) Where 7» is a Wavelength of the light beam; and n is a refractive index of the ?rst protective ?lm to a light

mounting a second stamper platen for forming a second recording surface on a second die; positioning the ?rst die and second die so as to keep a space

having the Wavelength 7».

therebetWeen and to arrange the ?rst stamper platen to

This invention further provides an information recording

face the second stamper platen;

medium, Which comprises; a substrate having a couple of recording surfaces facing to each other and each provided With emboss pits or guid

ing grooves;

20

a couple of re?ective ?lms each formed on each of the

recording surfaces of the substrate; a couple of ?rst protective ?lms each formed on each of the

re?ective ?lm; and

double surface substrate having a thickness of not more

a couple of light incident surfaces each constituting an outermost surface; Wherein a light beam to be irradiated is designed to be

than 1.2 mm.

Additional objects and advantages of the invention Will be set forth in the description Which folloWs, and in part Will be obvious from the description, or may be learned by practice of the invention. The objects and advantages of the invention

entered and re?ected through the couple of light incident surfaces, a recorded information being reproduced based on changes in light intensity of the re?ected light

may be realiZed and obtained by means of the instrumentali

beam; a distance betWeen one of the light incident surfaces of the information recording medium to the other is not more than 1.2 mm; a distance betWeen the recording surface of the substrate

?lling the space formed betWeen the ?rst die and second die With a heated and ?uidiZed resinous material; bringing the ?rst die and second die close to each other thereby adjusting an interval betWeen the ?rst die and second die to a predetermined distance; and alloWing the resinous material ?lled betWeen the ?rst die and second die to cool and solidify thereby to obtain a

ties and combinations particularly pointed out hereinafter. 35

and the light incident surface formed over the recording surface is smaller than a thickness of the substrate; and Wherein a surface roughness “R” of the couple of light incident surfaces meets a relationship represented by the folloW

BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWING

The accompanying draWings, Which are incorporated in and constitute a part of the speci?cation, illustrate presently preferred embodiments of the invention, and together With the

general description given above and the detailed description of the preferred embodiments given beloW, serve to explain the principles of the invention.

ing formula (1):

FIG. 1 is a cross-sectional vieW schematically shoWing one

Rik/(8n) (1) Where 7» is a Wavelength of the light beam; and n is a refractive index of the ?rst protective ?lm to a light

example of an information recording medium according to 45

FIG. 2 is a graph shoWing a relationship betWeen the ?lm thickness and re?ectance of a re?ective ?lm;

having the Wavelength 7». This invention further provides an information recording

FIG. 3 is a graph illustrating the dependency of the ?lm

medium, Which comprises; a surface substrate having a light incident surface and an

50

emboss pit surface provided With emboss pits and facing the light incident surface;

FIG. 5 is a schematic vieW of a die for forming a disk

the surface substrate; 55

emboss pi t surface;

the supporting substrate; and 60

FIG. 7 is a cross-sectional vieW schematically shoWing still another example of an information recording medium

according to this invention; FIG. 8 is a cross-sectional vieW schematically shoWing still another example of an information recording medium

according to this invention;

tive ?lm; a second record surface is constituted by the emboss spit surface of the supporting substrate and the second re?ective ?lm; and Wherein

substrate to be employed for the manufacture of the informa tion recording medium shoWn in FIG. 4; FIG. 6 is a cross-sectional vieW schematically shoWing still another example of an information recording medium

according to this invention;

a second re?ective ?lm formed on the emboss pit surface of

a transparent adhesive layerbonding the ?rst re?ective ?lm and the second re?ective ?lm; Wherein a ?rst record surface is constituted by the emboss spit surface of the surface substrate and the ?rst re?ec

thickness of a re?ective ?lm on the light Wavelength; FIG. 4 is a cross-sectional vieW schematically shoWing another example of an information recording medium

according to this invention;

a ?rst re?ective ?lm formed on the emboss pit surface of

a supporting substrate having an emboss pit surface pro vided With emboss pits and a substrate surface facing the

this invention;

65

FIG. 9 is a cross-sectional vieW schematically shoWing still another example of an information recording medium

according to this invention;

US RE43,969 E 5

6

FIG. 10 is a cross-sectional vieW schematically showing still another example of an information recording medium

?lm thickness of the protective ?lm 4 can be considered as

corresponding to the thickness of the substrate according to the conventional optical disk. According to the optical disk of this invention, the distance from the embossed surface (recording surface) to the light

according to this invention; FIG. 11 is a cross-sectional vieW schematically shoWing a

method of injection-molding the information recording medium shoWn in FIG. 10; FIGS. 12A to 12D are perspective vieWs illustrating the

incident surface is de?ned as being smaller than the thickness of the substrate 1, the thickness of the protective ?lm 4 is naturally smaller than the thickness of the substrate. There

steps of manufacturing the information recording medium shoWn in FIG. 10; FIG. 13 is a cross-sectional vieW schematically shoWing still another example of an information recording medium

fore, the optical disk of this invention Will be hardly in?u enced by the restriction due to the thickness of the substrate on the tilt margin, thus making it easy to increase the record

according to this invention;

ing density.

FIG. 14 is a schematic vieW for illustrating the re?ectance and the transmittance of the recording surface in a 2-ply

According to the information recording medium of this invention, the surface roughness “R” of the surface to Which a light beam is to be irradiated, ie the light incident surface

optical disk; FIG. 15 is a graph shoWing a relationship betWeen the ?lm thickness and re?ectance of a re?ective ?lm; FIG. 16 is a graph shoWing a relationship betWeen the ?lm thickness and re?ectance of a re?ective ?lm; FIG. 17 is a graph shoWing a relationship betWeen the ?lm thickness and re?ectance of a re?ective ?lm; FIG. 18 is a graph shoWing a relationship betWeen the ?lm thickness and re?ectance of a re?ective ?lm; FIG. 19 is a graph shoWing a relationship betWeen the ?lm thickness and re?ectance of a re?ective ?lm; FIGS. 20A and 20B are cross-sectional vieWs schemati

cally shoWing still another example of an information record ing medium according to this invention; and FIG. 21 is a graph illustrating a relationship betWeen the Wavelength of light beam for recording and reproducing a data and the intensity of re?ected beam in a 2-ply disk.

is de?ned so as to meet a relationship represented by the

folloWing formula (1): 20

refractive index of the protective ?lm to a light having

the Wavelength 7». It becomes possible, by limiting the surface roughness of 25

30

DETAILED DESCRIPTION OF THE INVENTION

This invention Will be further explained in detail With ref

35

EXAMPLE 1 40

example of an optical disk according to this example. In the optical disk shoWn in FIG. 1, one of the surfaces of a disk substrate 1 having a thickness of 1.2 mm is formed into a

recording surface on Which emboss pits 2 are formed in conformity With a recorded data. The thickness of the sub strate 1 may be suitably selected as long as the thickness in the range of from 0.6 mm to 1.2 mm. The surface of this recording surface provided With the emboss pits 2 is covered With a re?ective ?lm 3 and then With an over-coating consisting of a

protective ?lm (?rst protective ?lm) 4. In the case of the optical disk shoWn in FIG. 1, The surface of the protective ?lm 4 is the light incident surface. The readout of the recorded data stored in the disk can be performed as folloWs. Namely, as shoWn in FIG. 1, a light beam 5 is converged by an objective lens 6 and then enters

45

50

the aforementioned formula (1 ). Further, in this case also, it is an indispensable requirement for the information recording medium of this invention that the distance from the recording surface to the light incident surface should be smaller than the

The embossing of the recording surface of the disk sub 55

strate is formed With a siZe of about M (8n) in relative to the

wavelength 7» of a light beam to be employed for the repro duction of a recorded data (Wherein n is a refractive index of

the surface protective ?lm to a light having the aforemen

tioned Wavelength 7») The distance from the recording surface 60

enters not from the protective ?lm side but from the transpar ent substrate side, and is re?ected by the emboss formed on the surface opposite to the light incident surface of the sub strate, thus enabling the emboss data to be read. By contrast, in the case of the optical disk having a structure as shoWn in

from Which a light beam is to be irradiated becomes the light incident surface in the information recording medium of this invention. For example, When this second protective ?lm is formed on the surface of the ?rst protective ?lm, the surface of the second protective ?lm becomes the light incident sur face. It is also required in this case that the surface roughness R of the light incident surface constituted by the second

thickness of the substrate.

detected as the recorded data of the emboss pits.

FIG. 1 hoWever, since the data is to be reproduced from the embossed surface formed on the surface of the substrate, the

medium of this invention, to further include a second protec tive ?lm Which is to be formed on the ?rst protective ?lm as mentioned hereinafter. In any case, the outermost surface

protective ?lm should meet the relationship represented by

through the protective ?lm 4. The light beam is then re?ected by the re?ective ?lm 3, thus producing a light re?ection accompanying changes in light intensity, Which are then

According to the conventional optical disk, light beam

the light incident surface as described above thereby ensuring the ?atness of the light incident surface, to minimiZe the light-diffracting phenomenon at the light incident surface. Additionally, if the surface of the optical disk is ?at as de?ned above, dust can be hardly attached to the surface of the optical disk, thus improving a dust adhesion preventive effect of the optical disk. Moreover, if the surface of the optical disk is ?at as de?ned above, it is also possible to obtain the effect that the optical disk can be prevented from being contacted With the objective lens. By the Way, more preferable surface roughness of the light incident surface is not higher than a half of M (8n),

ie not higher than k/(l 6n). It is possible, according to the information recording

erence to the examples of this invention.

FIG. 1 is a cross-sectional vieW schematically shoWing one

Rik/(8n) (1) Wherein 7» is a Wavelength of the light beam; and n is a

65

of the disk substrate to the surface to be irradiated (light

incident surface) should preferably be at least 10 times higher than the magnitude of the embossing in vieW of the smoothing of the light incident surface. Accordingly, the distance from the recording surface of the disk substrate to the light incident surface should preferably be 5M (4n). Further, in vieW of shortening the Wavelength of the light beam and a tilt margin involved in highly enhancing the NA of the objective lens, the

US RE43,969 E 8

7 distance from the recording surface of the disk substrate to the light incident surface should preferably be 0.1 mm or less.

By the Way, the re?ective ?lm in this example Was formed

using an Al-based alloy ?lm, and the Wavelength of the light

The optical disk shoWn in FIG. 1 can be manufactured as folloWs. First of all, the re?ective ?lm 3 is formed on the

beam to be irradiated Was set to 650 nm. The graph of FIG. 2

recording surface of the disk substrate 1. In this case, the re?ective ?lm 3 can be deposited on the recording surface of the disk substrate 1 by the vapor deposition or sputtering of a material for the re?ective ?lm. The protective ?lm 4 to be placed on the surface of this

re?ective ?lm 3 is set to about 14 nm, the re?ectance becomes

re?ective ?lm 3 can be formed by making use of a conven

protective ?lm 4. Accordingly, the re?ectance at the surface of the re?ective ?lm can be obtained by subtracting the surface re?ection from the re?ectance shoWn in this graph. Speci? cally, since the re?ectance When the thickness of the re?ective

shoWs that under this condition, When the ?lm thickness of the 45%, While When the ?lm thickness of the re?ective ?lm 3 is set to about 40 nm, the re?ectance becomes almost saturated.

The re?ectance represented by the curve shoWn in this graph includes also a surface re?ection from the surface of the

tional ultraviolet-curing resin for instance. Namely, the pro tective ?lm 4 is at ?rst coated on the surface of the re?ective

?lm 3 by means of a spin coating method for instance thereby to form a resin ?lm, and then irradiated With ultraviolet rays

?lm is Zero corresponds to the surface re?ection of the pro tective ?lm 4, the re?ectance of the re?ective ?lm can be

thereby to cure the resin ?lm, thus forming the protective ?lm 4. The thickness of this over-coating protective ?lm 4 may be in the range of from several microns to several millimeters in

obtained by subtracting the value (about 5%) of the re?ec

practical vieW point. More preferably, the thickness of this

tance When the thickness of the re?ective ?lm is Zero from the re?ectance shoWn in this graph in the case of the curve shoWn in FIG. 2. FIG. 3 illustrates the dependency of the ?lm thickness of a

over-coating protective ?lm 4 should be not more than 0.6 mm, most preferably in the range of 0.0001 to 0.1 mm. Addi

20

tionally, the thickness of the protective ?lm 4 should prefer ably be such that does not optically interfere With the re?ec tive ?lm 3. As for the material for the protective ?lm 4, it is not restricted to ultraviolet-curing resins, but may be any material as long as it is capable of alloWing a light beam for the

re?ective ?lm on the light Wavelength When the re?ectance becomes 45% or saturated. By the Way, the re?ective ?lm in this example Was formed using anAl-based alloy ?lm, and the 25

Wavelength of the light beam Was set to 400 to 800 nm.

reproduction of data to be transmitted therethrough and is

In the graph shoWn in FIG. 3, the line “a” indicates a ?lm thickness Where the re?ectance becomes 45%, While the line

stable environmentally and thermally. For example, the pro

“b” indicates a ?lm thickness Where the re?ectance becomes

tective ?lm 4 may be constituted by a dielectric material.

More speci?cally, the protective ?lm 4 may be formed by

30

means of a vacuum deposition method or a sputtering method

employing SiO2, SiO, AlN, A1203, ZrO2, TiO2, Ta2O3, ZnS, Si, Ge or a mixture thereof.

?lm giving a re?ectance of 45% Was in the range of 13 to 14 nm, While the ?lm thickness of the re?ective ?lm giving a.

This protective ?lm 4 may be omitted provided that the re?ective ?lm 3 per se is formed of a stable ?lm. The disk substrate 1 having a thickness of 1.2 mm and

35

saturated re?ectance Was about 40 nm.

Since the re?ectance is set to 45 to 85% according to the

being useful for the manufacture of the optical disk of this example can be manufactured by means ofan injection mold ing method Which is commonly employed for the manufac ture of the conventional CD and DVD. For example, a master

saturated. As shoWn in this graph, the dependency of the ?lm thickness of the re?ective ?lm on the light Wavelength Within the range of 400 to 800 nm is relatively small. Further, Within this range of Wavelength, the ?lm thickness of the re?ective

speci?cation of DVD-ROM, the re?ectance of the re?ective ?lm of the optical disk according to this invention is required to be 45% or more thereby making it possible to secure the

platen in Which information is stored in advance is mounted on one of the dies of an injection molding machine, and then

compatibility With DVD-ROM in the reproduction of data. The graph shoWn in FIG. 3 indicates that for the realiZation of this re?ectance, the ?lm thickness of the re?ective ?lm is

an injection molding is performed after adjusting the space

required to set to 14 nm or more. Further, for the purpose of

betWeen a couple of dies in such a Way that the thickness of the substrate after the molding thereof becomes 1.2 mm, thus manufacturing a disk substrate having a thickness of 1.2 mm.

As mentioned above, according to the conventional optical disk, since recorded data is designed to be reproduced by irradiating a light beam from the substrate side, the substrate is required to have a capability of permitting a light beam for the reproduction of data to transmit therethrough. Whereas, according to the optical disk of this invention, since recorded data is designed to be reproduced by irradiating a light beam from the protective ?lm side, the substrate is not necessarily required to be transparent. Since the light beam is irradiated from the protective ?lm side as mentioned above, the problem of birefringence of the substrate can be disregarded. There

40

45

re?ective ?lm to a ?lm thickness Where the re?ectance

thereof is saturated. For this purpose, the ?lm thickness of the re?ective ?lm should preferably be set to 40 nm or more.

The re?ective ?lm consisting of the Al -based alloy ?lm and 50

of data using a green or blue light beam in future. 55

optical recording medium shoWn in FIG. 1.

EXAMPLE 2

FIG. 4 is a cross-sectional vieW schematically shoWing one

example of an optical disk according to this example. In the optical disk shoWn in FIG. 4, one of the surfaces of a disk 60

substrate 1 having a thickness of 1.2 mm is formed into a

recording surface on Which emboss pits 2 are formed in conformity With a recorded data. The surface of this recording

employed. FIG. 2 shoWs a graph illustrating a relationship betWeen the ?lm thickness and re?ectance of the re?ective ?lm of the

manufactured as mentioned above is minimal in light Wave

length dependency, so that it is possible to apply the re?ective ?lm With this magnitude of ?lm thickness to the reproduction

fore, there is not any particular limitation as to the material of the substrate as long as the material is excellent in environ

mental resistance, heat resistance and Workability. For example, materials such as ABS resin, polyethylene resin, polystyrene resin, etc. Which are inexpensive as compared With the materials employed conventionally can be

securing a ?xed re?ectance by suppressing the ?uctuation in ?lm thickness of the re?ective ?lm, it is preferable to set the

65

surface provided With the emboss pits 2 is covered by a re?ective ?lm 3, and then cover-coated With a ?rst protective ?lm 4 and a second protective ?lm 18 in the mentioned order. In the case of the optical disk shoWn in FIG. 4, the surface of the second protective ?lm 18 is the light incident surface.

US RE43,969 E 9

10

The readout of the recorded data stored in the disk can be performed as follows. Namely, as shoWn in FIG. 4, a light

Accordingly, in the case Where the optical disk is consti tuted by a 2-ply structure of protective ?lms as shoWn in FIG. 4, the second protective ?lm 18 is required to be formed of a transparent material having a refractive index n2 Which is larger than or equivalent to the refractive index nl of the ?rst

beam 5 is converged by an objective lens 6 and then enters

through the second protective ?lm 18. The light beam is then re?ected by the re?ective ?lm 3, thus producing a light re?ec tion accompanying changes in light intensity, Which are then detected as recorded data of the emboss pits. Thezdisk substrate 1 having a thickness of 1.2 mm, the

protective ?lm 4. According to the optical disk of this example, since the ?rst protective ?lm 4 is covered by the second protective ?lm 18,

emboss pits 2, the re?ective ?lm 3 and the ?rst protective ?lm 4 all constituting the optical disk of this example can be

it becomes possible not only to enhance the mechanical strength of the surface of the disk, but also to prevent the

constructed in the same manner as those of the aforemen

surface of the disk from being damaged during the handling

tioned optical disk of Example 1.

of the disk.

The second protective ?lm 18 to be placed on the surface of the ?rst protective ?lm 4 can be formed by making use of a

EXAMPLE 3

conventional ultraviolet-curing resin for instance. Namely, an ultraviolet-curing resin for instance is at ?rst coated on the

FIG. 5 is a cross-sectional vieW schematically shoWing one

surface of the ?rst protective ?lm 4 by means of a spin coating method thereby to form a resin ?lm, and then irradiated With ultraviolet rays thereby to cure the resin ?lm, thus forming the second protective ?lm 18. The thickness of this over-coating second protective ?lm 18 may be in the range of from several microns to several millimeters in practical vieW point. More

example of an optical disk according to this example. In the optical disk shoWn in FIG. 4, one of the surfaces of a disk substrate 25 having a thickness of 1.2 nm is provided With 20

25

27, a ?rst protective ?lm 28 constituting a loWer protective ?lm, a recording ?lm 29, and a second protective ?lm 30 constituting a upper protective ?lm in the mentioned order. The surface of this second protective ?lm 30 is further over coated by a third protective ?lm 31. In the case of the optical disk shoWn in FIG. 5, the surface of the third protective ?lm 31 is the light incident surface.

30

The readout of the recorded data stored in the disk can be performed as folloWs. Namely, as shoWn in FIG. 5, a light beam 5 is converged by an objective lens 6 and then enters

preferably, the thickness of this over-coating second protec tive ?lm 18 should be not more than 0.6 mm. Further, in vieW

of the ?lm thickness distribution of the ultraviolet-curing resin that Will be obtained by means of a spin-coating method, the thickness of this over-coating second protective ?lm 18 should preferably be in the range of 0.0001 to 0.1 mm in

practical vieWpoint. Additionally, the thickness of the second protective ?lm 18 should preferably be such that does not optically interfere With the re?ective ?lm 3. As for the material for the second protective ?lm 18, it is not restricted to ultraviolet-curing resins, but may be any material as long as it is capable of alloWing a light beam for the reproduction of data to be transmitted therethrough and is stable environmentally and thermally. For example, the sec ond protective ?lm 18 may be constituted by a dielectric material. More speci?cally, the second protective ?lm 18 may

through the third protective ?lm 31. The light beam is then re?ected by the re?ective ?lm 3, thus producing a light re?ec tion accompanying changes in light intensity due to the 35

40

TiO2, Ta2O3, ZnS, Si, Ge or a mixture thereof. Further, this second protective ?lm 18 is not limited to the aforementioned materials and to the aforementioned ?lm

forming method, but may be made from any materials Which are transparent to the Wavelength of light to be employed. For

45

example, a ?lm-like or a plate-like transparent resin having a thickness ranging from 0.0001 mm to 0.6 mm may be employed. These resin ?lm or plate may be placed on the ?rst

protective ?lm 4 at the occasion of spin-coating the ?rst protective ?lm 4, and then UV-irradiated and cured in a UV furnace, thus causing the resin ?lm orplate to be adhered onto the ?rst protective ?lm 4. HoWever, the refractive index of the second protective ?lm 18 and the refractive index of the ?rst protective ?lm 4 should

be suitably selected to meet the folloWing relationship. Spe ci?cally, the refractive index n2 of the second protective ?lm 18 at the Wavelength of the light beam to be employed for the reproduction of data is required to be larger than or equivalent

riorate.

styrene resin, glass, a metal such as Al, an alloy and ceramics. The surface of the optical disk substrate 25 constructed With any of these materials is then provided With groove tracks, land tracks, preformat marks, etc. depending on a recording format. The re?ective ?lm 27 has not only the effect of optically

enhancing the optical changes of the recording ?lm 29 to be 50

27 thereby to enhance the reproducing signal, but also the effect of cooling the recording ?lm 29. The re?ective ?lm 27 can be formed by depositing, by means of vacuum deposition method or a sputtering method, a metallic material such as

Au, Al, Cu, Ni4Cr or an alloy containing any of these mate 55

rial as a main component. The ?lm thickness of the re?ective ?lm 27 may be several nanometers to several micrometers in

practical vieWpoint. The recording ?lm 29 can be constituted by a phase-chang

ing material Whose crystal structure is adapted to be changed by the condition of irradiating a light beam. Examples of this 60

?lm 18 is smaller than the refractive index of the ?rst protec

tive ?lm 4 (n l>n2), the light re?ection at the interface betWeen the second protective ?lm 18 and the ?rst protective ?lm 4 becomes larger, Whereby the signal from the recording sur face is deteriorated and the light ef?ciency is caused to dete

ylmethacrylate (PMMA), polycarbonate resin, epoxy resin,

formed via the loWer protective ?lm 28 on the re?ective ?lm

to the refractive index nl of the ?rst protective ?lm 4 at the

Wavelength of the light beam to be employed for the repro duction of data. If the refractive index of the second protective

recording marks, the changes of Which are then detected as recorded data. This disk substrate 25 can be constituted by a material

Which is stable and minimal in change With time. Examples of speci?c useful materials are acrylic resin such as polymeth

be formed by means of a vacuum deposition method or a

sputtering method employing SiO2, SiO, AlN, A1203, ZrO2,

guiding grooves 26 to be used for the tracking of light beam 5. On this guiding grooves 26 are further formed a re?ective ?lm

phase-changing type material are chalcogenide type amor phous semiconductor materials such as GeTe type, TeSe type, GeSbSe type, TeO,C type, lnSe type and GeSbTe type amor

phous semiconductor materials and compound semiconduc tor material such as lnSb type, GaSb type and lnSbTe type 65

compound semiconductor materials. The recording ?lm 29 can be formed by means of a vacuum deposition method or a

sputtering method employing above materials. The ?lm

US RE43,969 E 11

12

thickness of the recording ?lm 29 may be several nanometers

the fourth protective ?lm and the third protective ?lm 31 becomes larger, Whereby the signal from the recording sur face is deteriorated and the light e?iciency is caused to dete

to several micrometers in practical vieWpoint. The loWer protective ?lm 28 and the upper protective ?lm 30 are laminated With the recording ?lm 29 being interposed

riorate. Accordingly, in the case Where the optical disk is consti

therebetWeen, thereby functioning to prevent the recording ?lm 29 from being dispersed or holed due to the irradiation of a recording beam. The loWer protective ?lm 28 and the upper protective ?lm 30 are also effective in controlling the heat

tuted by a 2-ply structure of protective ?lms, the fourth pro tective ?lm constituting an outermost surface is required to be formed of a transparent material having a refractive index n4 Which is larger than or equivalent to the refractive index n3 of

diffusion in the heating and cooling of the recording ?lm 29 at the occasion of recording. These loWer protective ?lm 28 and

the third protective ?lm 31.

upper protective ?lm 30 can be formed by means of a vacuum

deposition method or a sputtering method employing SiO2, SiO, AlN, A1203, ZrO2, TiO2, Ta2O3, ZnS, Si, Ge or a mixture thereof. The ?lm thickness of these loWer protective ?lm 28

EXAMPLE 4

FIG. 6 is a cross-sectional vieW schematically shoWing one

example of an optical disk according to this example. In the optical disk shoWn in FIG. 6, both top and back surfaces of a

and upper protective ?lm 30 may be several nanometers to

several micrometers in practical vieWpoint.

The over-coating protective ?lm (third protective ?lm) 31

disk substrate 13 having a thickness of 1.2 mm are formed into a recording surface on Which emboss pits 2 are formed in

to be formed on the surface of this upper protective ?lm

(second protective ?lm) 30 is provided for the purpose of preventing the phase-changing optical disk from being con taminated during the handling of the optical disk, and can be normally formed using a ultraviolet-curing resin. Namely, an

20

ultraviolet-curing resin for instance is at ?rst coated on the surface of the upper protective ?lm 30 by means of a spin

coating method thereby to form a resin ?lm, and then irradi ated With ultraviolet rays thereby to cure the resin ?lm, thus

tute individually the light incident surfaces. 25

forming the over-coating protective ?lm 31. The thickness of this over-coating protective ?lm 31 may be in the range of from several microns to several millimeters

in practical vieW point. More preferably, the thickness of this over-coating protective ?lm 31 should be not more than 0.6 mm. On the other hand, the loWer limit in thickness of the third protective ?lm 31 should preferably be 5N (4n) or more (Wherein 7» is a Wavelength of the light beam; and n is a refractive index of the third protective ?lm to a light having a

30

35

FIG. 7 shoWs schematically one example of a mold to be

employed for inj ection-molding a disk substrate 13 to be

employed for manufacturing the optical disk of this example 40

the A surface and a stamper 7b for the B surface are respec 45

In the foregoing explanation, a phase-changing recording 50

protective ?lm 31, thereby making the surface of the optical disk into a 2-ply protective ?lm structure. This structure is 55

being damaged during the handling of the optical disk. HoWever, the refractive index of the fourth protective ?lm and the refractive index of the third protective ?lm 31 should be suitably selected to meet the folloWing relationship. Spe ci?cally, the refractive index n4 of the fourth protective ?lm at the Wavelength of the light beam to be employed for the reproduction of data is required to be larger than or equivalent

tively manufactured at ?rst by making use of a conventional mastering. Then, a central hole 8 is accurately formed at the center of the stamper 7a for the A surface. LikeWise, a central hole 14 is accurately formed at the center of the stamper 7b for the B surface. A projection 16 having a diameter corresponding to the central hole 8 of the stamper 7a for theA surface is formed at the central portion of the inner surface of the mold 9. Like Wise, a projection 17 having a diameter corresponding to the central hole 14 of the stamper 7b for the B surface is formed at the central portion of the inner surface of the mold 15. By

providing these projections 16 and 17, the central hole 8 of the stamper 7a for the A surface can be accurately aligned With

60

to the refractive index n3 of the third protective ?lm 31 at the

Wavelength of the light beam to be employed for the repro duction of data. If the refractive index of the fourth protective ?lm is smaller than the refractive index of the third protective ?lm 31 (n3>n4), the light re?ection at the interface betWeen

and having a thickness of 1.2 mm and a recording surface on

both sides thereof. If it is designated that one of the surface of the disk: is anA surface, and the other surface is a B surface, a stamper 7a for

erably be in the range of 0.0001 to 0.1 mm in practical vieW

effective in enhancing the mechanical strength of the surface of the optical disk and in preventing the optical disk from

secure a recording capacity Which is tWice as large as that of

the single recording surface.

point. Additionally, the thickness of the over-coating protec

medium constituted by a 4-ply structure has been explained as one example. HoWever, each layer may be formed of a multi layer depending on the performance to be demanded. For example, a fourth protective ?lm may be formed on the

through both of the protective ?lms 4. The light beam is then re?ected by the re?ective ?lm 3, thus producing a light re?ec tion accompanying changes in light intensity, Which are then detected as recorded data of the emboss pits. Since the record

thickness of this over-coating protective ?lm 31 should pref tive ?lm 31 should preferably be such that does not optically interfere With the re?ective ?lm 27.

The readout of the recorded data stored in the disk can be performed as folloWs. Namely, as shoWn in FIG. 6, a light beam 5 is converged by an objective lens 6 and then enters

ing surface is formed on both surfaces of the optical disk according to this example, the reproduction of data can be effected from both surfaces, thereby making it possible to

Wavelength of 7»). If the ?lm thickness of the third protective ?lm 31 is less than 5M (4n), it becomes di?icult to reproduc ing the recorded data normally, since a multi-interfering effect of the light beam tends to occur. Further, in vieW of the ?lm thickness distribution of the ultraviolet-curing resin that Will be obtained by means of a spin-coating method, the

conformity With a recorded data. Each surface of these recording surfaces provided With the emboss pits 2 are cov ered by a re?ective ?lm 3, and then cover-coated With a protective ?lm 4. In the case of the optical disk shoWn in FIG. 6, the surfaces of this couple of the protective ?lms 4 consti

65

the central hole 14 of the stamper 7b for the B surface. Then, the stamper 7a for the A surface is mounted on the inner surface of the mold 9 for injection molding in such a manner that the recording surface of the stamper 7a is directed inside and the projection 16 of the mold 9 is inserted into the central hole 8 of the stamper 7a for the A surface. LikeWise, the stamper 7b for the B surface is mounted on the inner surface of the mold 15 disposed to face the mold 9 in such a manner that the recording surface of the stamper 7b is directed inside and the projection 17 of the mold 15 is inserted

US RE43,969 E 13

14

into the central hole 14 of the stamper 7b for the B surface. Under the condition Where these projections 16 and 17 are inserted into the central holes 8 and 14 of the stampers, respectively, the central hole 8 of the stamper 7a for the A

shoWn in FIG. 8, the surfaces of this couple of the second

protective ?lms 18 constitute individually the light incident surface.

The structure of the optical disk according to this example is the same as that of Example 2 except that the recording

surface is adjusted to accurately align With the central hole 14 of the stamper 7b for the B surface. Then, under the condition Where the recording surface of the stamper 7a for the A surface is disposed to face the recording surface of the stamper 7b for the B surface, a heated

substrate. Therefore, the disk substrate 13 having a thickness of 1.2 mm and constituting the optical disk of this example

and molten resin is introduced from the resin inlet port 12 into

the space betWeen these recording surfaces. Thereafter, either

Example 4, and other components such as emboss pits 2, re?ective ?lm 3, ?rst protective ?lm 4 and second protective

the stamper 7a for the A surface or the stamper 7b for the B

?lm 18 can be constructed in the same manner as explained in

surface is moved forWard thereby to adjust the interval betWeen the stamper 7a for the A surface and the stamper 7b for the B surface to a predetermined siZe. Speci?cally, the interval betWeen the stamper 7a for the A surface and the

Example 1.

surface and other ?lms are formed on both surface of the disk

can be constructed in the same manner as explained in

The readout of the recorded data stored in the disk can be performed as folloWs. Namely, as shoWn in FIG. 8, a pair of

light beams 5 and 20 are converged by objective lens 6 and 21, respectively, and then alloWed to enter through the second protective ?lms 18 disposed on both sides of the disk. The light beams are then re?ected by the re?ective ?lm 3, thus

stamper 7b for the B surface is set to such that the thickness of the substrate after the cooling or curing thereof becomes 1.2 mm.

As a result of the aforementioned process, a disk substrate

20

producing a light re?ection accompanying changes in light

13 having a thickness of 1.2 mm and provided With recording

intensity, Which are then detected as recorded data of the

surfaces on both sides thereof can be molded by a single

emboss pits. Since the recording surface is formed on both surfaces of the optical disk according to this example, the reproduction of data can be effected from both surfaces, thereby making it possible to secure a recording capacity Which is tWice as large as that of the single recording surface. The second protective ?lm 18 to be placed on the surface of the ?rst protective ?lm 4 can be formed by making use of a conventional ultraviolet-curing resin for instance. Namely, an ultraviolet-curing resin for instance is at ?rst coated on the surface of the ?rst protective ?lm 4 by means of a spin coating method thereby to form a resin ?lm, and then irradiated With ultraviolet rays thereby to cure the resin ?lm, thus forming the second protective ?lm 18. This couple of the second protective ?lm 18 can be formed

injection molding step. The deposition of the re?ective ?lm 3 on these recording surfaces can be performed by depositing a material for the

25

re?ection ?lm by means of a vacuum deposition method or a

sputtering method. More speci?cally, an evaporation source or a sputtering target material is placed on both sides of the

disk, thereby positioning a pair of evaporation sources or sputtering target materials so as to face each other. Then, the evaporation sources or sputtering target materials are alloWed

30

to evaporate or sputter, thereby simultaneously depositing a pair of re?ective ?lms on both recording surfaces. Alterna tively, it is also possible to mask one of the recording surfaces With a masking material and to perform the aforementioned deposition, and thereafter, the same procedures are repeated,

35

one after another or concurrently on both surfaces of the disk.

thereby successively performing the deposition of the re?ec tive ?lm one by one.

The over-coating of the protective ?lm 4 can be performed by a process Wherein a masking material is applied at ?rst to one of the re?ective ?lm 3, a UV-curing resin is spin-coated on this one of the re?ective ?lm 3, a UV-curing resin is then spin-coated on the other one of the re?ective ?lm 3 in the

40

thereby forming a couple of resin ?lms. Thereafter, the result

same manner, then the resultant resin ?lms are cured in a UV

furnace, thus forming the protective ?lm 4. Alternatively, the

Namely, if the second protective ?lm 18 is to be formed one after another on both surfaces of the disk, a masking material is applied at ?rst onto one of the ?rst protective ?lm, and then a UV-curing resin is spin-coated on this one of the ?rst pro tective ?lm. Then, the same procedures as mentioned above are repeated on the other one of the ?rst protective ?lm,

45

ant resin ?lms are cured in a UV furnace, thus easily forming the second protective ?lm 18. On the other hand, if a couple of

over-coating of the protective ?lm 4 can be performed simul

the second protective ?lms 18 are to be formed simulta

taneously on both re?ective ?lms 3. In this case, the disk should be rotatably supported on a suitable tool and then a

neously on both ?rst protective ?lms 4, the folloWing proce dures can be employed. In this case, the disk should be rotat ably supported on a suitable tool and then a UV-curing resin

UV-curing resin is applied through spin-coating to both sides of the disk thereby to form a resin ?lm on the re?ective ?lms 3. The resultant resin ?lms on the re?ective ?lms 3 are then

50

alloWed to pass through a pair of facing UV lamps provided in

then alloWed to pass through a pair of facing UV lamps

a UV fumace thereby to cure the resin ?lms. By the utiliZation of this process, the over-coating of protective ?lms 4 can be

performed simultaneously on both re?ective ?lms 3.

55

EXAMPLE 5

FIG. 8 is a cross-sectional vieW schematically shoWing one

example of an optical disk according to this example. In the optical disk shoWn in FIG. 8, both top and back surfaces of a

60

disk substrate 13 having a thickness of 1.2 mm are formed into a recording surface on Which emboss pits 2 are formed in

and a second protective ?lm 18. In the case of the optical disk

provided in a UV furnace thereby to cure the resin ?lms. By the utiliZation of this process, the over-coating of the second protective ?lm 18 can be performed simultaneously on both ?rst protective ?lms 4. The thickness of this over-coating second protective ?lm 18 may be in the range of from several microns to several

millimeters in practical vieW point. More preferably, the thickness of this over-coating second protective ?lm 18 should be not more than 0.6 mm. Further, in vieW of the ?lm

thickness distribution of the ultraviolet-curing resin that Will be obtained by means of a spin-coating method, the thickness

conformity With a recorded data. The surfaces of these record

ing surfaces provided With the emboss pits 2 are covered respectively by a re?ective ?lm 3, by a ?rst protective ?lm 4

is applied through spin-coating to both sides of the disk thereby to form a resin ?lm on both ?rst protective ?lms 4. The resultant resin ?lms on both ?rst protective ?lms 4 are

65

of this over-coating second protective ?lm 18 should prefer ably be in the range of 0.0001 to 0.1 mm in practical vieW

point. Additionally, the thickness of the second protective

US RE43,969 E 15

16

?lm 18 should preferably be such that does not optically interfere With the re?ective ?lm 3. As for the material for the second protective ?lm 18, it is not restricted to ultraviolet-curing resins, but may be any material as long as it is capable of allowing a light beam for the reproduction of data to be transmitted therethrough and is stable environmentally and thermally. For example, the sec ond protective ?lm 18 may be constituted by a dielectric material. More speci?cally, the second protective ?lm 18 may

HoWever, because of the same reason as explained in the

aforementioned Example 2, When an optical disk is consti tuted by a 2-ply lamination structure of protective ?lm as shoWn in FIG. 8, the second protective ?lm 18 should be formed using a transparent material having a refractive index n2 Which is larger than or equivalent to the refractive index n 1

of the ?rst protective ?lm 4. The optical disk according to this example is constructed such that the second protective ?lm 18 is further laminated on each of the ?rst protective ?lms 4 formed on both sides of the disk. In the case of Example 3, the recording. surface is formed only one surface of the disk, ie a single recording

be formed by means of a vacuum deposition method or a

sputtering method employing SiO2, SiO, AlN, A1203, ZrO2, TiO2, Ta2O3, ZnS, Si, Ge or a mixture thereof. If the second protective ?lm 18 is to be simultaneously formed on both of the ?rst protective ?lms 4 by making use of

type. Whereas, in this example, the recording surface is formed also on the other side of the disk, thus making it into a double recording type. Since the optical disk is made into a double recording type, it is possible to secure a recording capacity Which is tWice as

these materials, an evaporation source or a sputtering target

material is placed on both sides of the disk, thereby position ing a pair of evaporation sources or sputtering target materials so as to face each other. Then, the evaporation sources or

sputtering target materials are alloWed to evaporate or sputter,

20

thereby simultaneously depositing a pair of the second pro tective ?lms 18 on both of the ?rst protective ?lms 4, respec tively. Alternatively, it is also possible to mask one of the ?rst protective ?lms 4 With a masking material and to perform the

deposition of the second protective ?lms 18, and thereafter

large as that of the optical disk of single recording type. According to the optical disk of this example, since both of the ?rst protective ?lms 4 are respectively covered by the second protective ?lm 18, it becomes possible not only to enhance the mechanical strength of both surfaces of the disk, but also to prevent both surfaces of the disk from being

damaged during the handling of the disk. 25

the same procedures as mentioned above are repeated,

EXAMPLE 6

thereby successively performing the deposition of the re?ec tive ?lm one by one.

Further, this second protective ?lm 18 is not limited to the aforementioned materials and to the aforementioned ?lm forming method, but may be made from any materials Which

The ?lm thickness of the couple of second protective ?lms 30

For example, in the optical disk shoWn in FIG. 8, the ?lm

are transparent to the Wavelength of light to be employed. For example, a ?lm-like or a plate-like transparent resin having a thickness ranging from 0.0001 mm to 0.6 mm may be

employed. These resin ?lm or plate may be placed on the ?rst protective ?lm 4 at the occasion of spin-coating the ?rst protective ?lm 4, and then UV-irradiated and cured in a UV furnace, thus causing the resin ?lm orplate to be adhered onto the ?rst protective ?lm 4. If it is desired to form the second protective ?lm 18 by adhering the aforementioned resin ?lm onto the ?rst protec

35

40

tive ?lm 4, a masking material is applied at ?rst onto one of the surfaces of the re?ective ?lm, and then a UV-curing resin is coated on the other surface of the re?ective ?lm. Then, the same procedures as mentioned above are repeated on the

EXAMPLE 7 45

spin-coated on these resin ?lms and then cured in a UV 50

18. The second protective ?lms 18 may be formed concur

rently. In this case, the disk should be rotatably supported on a suitable tool and then a UV-curing resin is applied through spin-coating to both sides of the disk thereby to form a resin ?lm on both ?rst protective ?lms 4. The resultant resin ?lms

55

on both ?rst protective ?lms 4 are then alloWed to pass

through a pair of facing UV lamps provided in a UV furnace thereby to cure the resin ?lms, thus concurrently forming the second protective ?lms 18. 60

the recorded data on both surfaces of the disk can be repro

65

duced by making use of an optical head having an identical

The thickness of the entire disk shoWn in Example 6 may be set to 1.2 mm by further adjusting the thickness of the substrate 13. For example, When the ?lm thickness of one of the second protective ?lms 18 is set to 0.1 mm, While the ?lm thickness of the other second protective ?lm 18 is set to 0.6 mm in the optical disk shoWn in FIG. 8, the thickness of the entire disk can be made into 1.2 mm by setting the thickness of the disk substrate 13 to 0.5 mm. As a result, the thickness of the optical disk can be made equivalent to that of the conventional CD and DVD, so that the compatibility in the handling of disk can be secured. EXAMPLE 8

If the thickness of the protective ?lm 18 formed on both sides of the disk is set to correspond With the operating dis tance of the light beam, and at the same time, if this couple of protective ?lms disposed on both top and back surfaces of the disk are made identical in thickness thereof With each other,

operation distance.

thickness of one of the second protective ?lms 18 is set to in the range of 0.0001 to 0.6 mm, While the ?lm thickness of the other second protective ?lm 18 is set to 0.6 mm. As a result, the folloWing advantages can be obtained. Namely, the sur face on one of the protective ?lms 18 that is thinner in ?lm thickness can be employed as a data-reproducing surface for an optical head having a shorter operating distance, While the surface on the other protective ?lm 18 that is larger in ?lm thickness can be employed as a data-reproducing surface for an optical head formed in conformity With the conventional

DVD speci?cation.

other surface of the re?ective ?lm, thereby forming a couple of resin ?lms for constituting the ?rst protective ?lms 4. Thereafter, a material for the second protective ?lm 18 is

furnace, thereby easily forming the second protective ?lms

18 formed on both sides of the disk shoWn in Example 5 may be modi?ed to become different from each other.

FIG. 9 is a cross-sectional vieW schematically shoWing one

example of an optical disk according to this example. In the optical disk shoWn in FIG. 9, both top and back surfaces of a disk substrate 34 having a thickness of 1.2 mm

are provided With guiding grooves 26 for the tracking of the light beams 5 and 32. The surface of the guiding grooves 26 is covered by a sequence of ?lms including, in the mentioning

Information recording medium and method of manufacturing resinous ...

Jun 2, 2009 - __. F163 352*?). I. I. I. —._l. 35;. 400 500. 600. 700. 800. WAVELENGTH [nm] ... 450 560 5150 6'00 6'50 760 750 800. WAVELENGTH [nm].

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