Renewable Energy 29 (2004) 1947–1963 www.elsevier.com/locate/renene

First in situ determination of ground and borehole thermal properties in Latin America P. Roth a, A. Georgiev a,,1, A. Busso b, E. Barraza a a b

Department of Mechanical Engineering, UTFSM, Valparaiso, Chile Department of Physics, FaCENa, UNNE, 3400 Corrientes, Argentina Received 9 October 2003; accepted 18 February 2004

Abstract The design of a ground heat exchanger for Underground Thermal Energy Storage (UTES) applications requires, among other parameters, knowledge of the thermal properties of the soil (thermal conductivity, borehole thermal resistance and undisturbed soil temperature). In situ determination of these properties can be done by installing a vertical borehole heat exchanger (BHE) and performing the so-called thermal response test (TRT). The present paper describes the results of a cooperative work between research groups of Chile and Argentina, which led to the first thermal response test performed in Latin America. A setup for implementing the TRT was prepared at the ‘‘Solar Energy Laboratory’’ of the Technical University Federico Santa Maria, Valparaiso, Chile. The test was realized over 9 days (24 June to 3 July 2003) while inlet and outlet fluid temperatures of the BHE and the ambient temperature were measured every minute. A comparison between conventional slope determination method, Geothermal Properties Measurement (GPM) data evaluation software based on numerical solutions to the differential equations governing the heat transfer processes and two variable-parameter fitting was performed in order to calculate the thermal conductivity and borehole thermal resistance. The detailed study of ground properties in different regions of Chile and Latin America (Argentina, Brazil) is a good precondition for future investigation and application of the Borehole Thermal Energy Storage (BTES) technology in the region. # 2004 Elsevier Ltd. All rights reserved. Keywords: Thermal response test; Ground thermal conductivity; Borehole thermal resistance



Corresponding author. P.O. Box 7, 4023 Plovdiv, Bulgaria. Tel.: +359-32-680829; fax: +359-32270270. E-mail address: [email protected] (A. Georgiev). 1 On leave from Department of Mechanics, Technical University of Sofia, branch Plovdiv, Bulgaria. 0960-1481/$ - see front matter # 2004 Elsevier Ltd. All rights reserved. doi:10.1016/j.renene.2004.02.014

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Nomenclature thermal diffusivity (k/C) (m2/s) volumetric specific heat capacity (J/m3 K) exponential integral borehole depth (m) heat injection rate (W) rate of energy input to the heat carrying fluid (heat from electric heaters þ pump and friction in hydraulic circuit) (W) q rate of system heat loss to the surrounding (W) R thermal resistance (W/m K) r radius (m) v T temperature ( C) v T0 undisturbed ground temperature ( C) t time (s) U overall heat transfer coefficient of the system (W/K) u independent variable c ¼ 0:5772 Euler’s constant k thermal conductivity of soil (W/m K) a C E1 H Q Qe

Subscripts amb ambient av average b borehole BHE borehole exchanger bot bottom exp experimental f fluid GPM Geothermal Properties Measurement in inlet LSM Line Source Model s side sim simulation th thermal out outlet

1. Introduction The accumulation of energy during 3 months and more is a problem all over the world. An interesting technical combination is a system consisting of solar collectors and Underground Thermal Energy Storage (UTES). There are certain experiences in the investigation of ground thermal properties, which are mainly a base for the development of the seasonal Borehole Thermal Energy Storage (BTES).

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Laboratory methods to study the ground properties are used—unfortunately their results are normally not correct. A vary effective method used for the determination of the ground thermal conductivity is the thermal response test (TRT). It has been in use since 1995 in IEA ECES countries but the method, equipment and evaluation procedure are still under development. Basically, a defined thermal load is applied to a borehole heat exchanger (BHE) and water flow and inlet and outlet temperatures are measured at regular intervals. The TRT was first presented by Mogensen [1]—his installation is designed as a stationary system. After that, a mobile conductivity measurement system appeared in Sweden [2,3] and the USA [4]. Evaluation of the data gathered during a TRT is based on a given conceptual model for the heat transfer processes occurring in the borehole and surrounding soil. The theoretical approach commonly used is based on the Line Source Model (LSM), which depends primarily on the thermal conductivity of the soil and the fluid-to-soil thermal resistance. Moreover, for data evaluation a logarithmic approximation to the exact solution is applied, which for times usually exceeding 10 h gives a maximal error of 2%. The theoretical basis of the thermal response test is presented by Hellstro¨m [5], Gehlin [6] and Kavanaugh and Rafferty [7]. Different types of BHEs were investigated to determine the borehole thermal resistance [8]. About 10 countries in the world are dealing nowadays with this type of investigation—e.g. Germany [9], Sweden [2], Canada, USA [4], Norway, Netherlands, England and Turkey [10]. The installation in Chile is the first one in Latin America, starting future development in this area—it studies the thermal conductivity, the thermal diffusivity and the temperature of the subsoil [11].

2. Preparation of the installation 2.1. Perforations and installation construction The location chosen was the experimental field the ‘‘Solar Energy Laboratory’’ of the Technical University Federico Santa Maria (UTFSM), Quilpue. The schematic diagram of the setup is shown in Fig. 1. In 2002 three perforations were made along a line to a depth of about 22 m. The soil at the site consists of three main layers. The data is presented in Table 1. The central perforation is a borehole with a depth of 16.9 m and a diameter of 15 cm. The borehole was subsequently grouted with a 12% bentonite mixture (commercial mane Max Gel, produced in Federal Summit, Houston, TX). In the center of the BHE four thermocouples of type K (Chromel/Alumel) were mounted at depths of 16.9, 10.7, 3.24 and 0.25 m. Two additional perforations were realized, one 0.4 m to the left of the BHE, the other 0.8m to its right. Thermocouples of type K were also installed in these perforations at depths of 20.5, 13.67, 6.84 and 0.25 m. These perforations were filled up again with the same soil. The U-pipe (Fig. 1) installed in the central borehole is of high density polyethylene (3/4 in. SDR 11) produced by ‘‘EMIN Ingenierı´a y Construccio´n’’, Antofagasta, Chile. Its characteristics are presented in Table 2.

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Fig. 1. Scheme of the test installation situated in the Solar Energy Laboratory of the UTFSM.

Connecting 3/4 in. copper pipes join the U-pipe to the heating system above the soil surface. A 2 kW electric heater was mounted in the installation case. The circulation pump is of the type PKM 60-1, made by Pedrollo, Italy. It has a nominal

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Table 1 Structure and parameters of the subsoil in town of Quilpue Depth (m)

Soil characterization

Density (t/m3)

Humidity (%)

0–0.6 (or 1.5)

Surface layer: clay with organic components. Expansive and retractil sand with colour changing between leadish brown-coffee to reddish brown-coffee Firm and compact silticlayed sand. Corresponds to Maicillo and residual metorised rock (rocks which oxidize and decompose in the same place) Natural sedimentary rock from the hill (fragmented dry)

1.7

Variable, depending on the water present at the site. Irrigable land

1.9–2.1

5–8

2.3–2.4

3–5

0.6 (or 1.5)–5 (or 7)

5 (or 7) and more

electrical power of 370 W, working at 2900 rpm with a flow rate between 5 and 40 l/min to a maximum height of 40 m. 2.2. Measurement equipment In the subsoil 12 thermocouples of type K (Chromel/Alumel) were installed (eight in the ground and four in the bentonite). A manual rotameter ‘‘Blue White industries 9509’’ with maximal flow rate of 7.5 l/min was used to measure the flow rate. Two Gemini Data Loggers with sensor of the type Standard Temperature Probe PB-4724 were used for monitoring the temperatures of the boreholes. Ambient temperature was measured with a Gemini Data Logger TGP—0017 with a caseintegrated sensor. The data loggers were programmed by means of the software GLM v2.8. Measurements were recorded in the memory of the logger and downloaded to the PC on a daily basis using the same software. The electrical power of the electrical heater and the circulating pump were measured with two different wattmeters, from AEG Berlin, Germany. The equipment was calibrated prior to the test. Table 2 Main characteristics of U-pipe 3/4 in. SDR 11 External diameter Internal diameter Density Melting temperature Working temperature Peak temperature (momentary) Thermal conductivity Coefficient of linear expansion

25 mm 20.4 mm 0.96 g/cm3 v 130 C v 90 C v 125 C 0.4 W/(m K) 0.17 mm/(m K)

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3. Thermal response test The TRT was carried out over 9 days from 24 June to 3 July 2003. The temperatures measured were—ambient temperature, inlet and outlet temperatures of the borehole. Additionally, although the flow rate was fixed at the constant value of 3.17 l/min, it was periodically measured and controlled. The electrical power was regulated and maintained constant at about 1000 W. The electrical power of the circulating pump was about 350 W. Both values were measured manually.

4. Response analysis 4.1. Theoretical background of evaluation methods applied The evaluation method widely accepted for simplicity and reasonable accuracy is based on the solution of the Line Source problem. A common difficulty quite often encountered when applying this model to analyse experimental data is that different time intervals lead to different slopes and this in turn, leads to different values for the soil properties sought. With this in mind and based on the results from a previous work on evaluation methods carried out by one of the authors [12], the data gathered were analysed and evaluated using the classical ‘‘slope determination technique’’, ‘‘two-variable parameter fitting’’ and with the aid of the Geothermal Properties Measurements (GPM) software. In this section a brief description of each method is presented. 4.1.1. Slope determination technique The method relies on the solution to the LSM problem. The equation for the temperature field as a function of time and radius around a line source with constant heat injection rate [13] may be used as an approximation of the heat injection from a BHE: _ ð 1 eu _ Q Q E1 ðr2 =4atÞ du ¼ ð1Þ Tðr; tÞ  Tðt ¼ 0Þ ¼ 4pkH r2 =4at u 4pkH For large values of the parameter at=r2 , the exponential integral can be approximated with the following simple relation:   4at at 2 5 ð2Þ E1 ðr =4atÞ ¼ ln 2  c r r2 The maximum error is 2.5% for at=r2  20 and 10% for at=r2  5. This condition means that accuracy increases as the thermal front reaches further beyond the borehole wall. Evaluating the line source temperature at the borehole radius (r ¼ rb ) and introducing the effect of the borehole thermal resistance, the fluid temperature can be

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written as:  _   4at  _ Q Q ln 2  c þ Rb þ T0 Tf ðtÞ ¼ r 4pkH H

ð3Þ

Eq. (3) can be re-written in a linear form as: Tf ðtÞ ¼ klnðtÞ þ m

with k ¼

_ Q 4pkH

ð4Þ

Hence, the thermal conductivity can be determined from the slope of the line resulting when plotting the fluid temperature against ln(t), therefore the name and basis of the evaluation method. Moreover, using Eq. (5) and the value of the thermal conductivity calculated leads to a number of borehole thermal resistances, one for every pair of fluid temperature and time. Suitably, a mean value is calculated:     H 1 4at Rb ¼ ðTf  T0 Þ  ln 2  c ð5Þ _ 4pk r Q

4.1.2. Two-variable parameter fitting The need for a more interval-independent evaluation technique led to fit the data using as fitting function Eq. (3) with the thermal conductivity and the borehole thermal resistances left as the two variable parameters. For the analysis, the commercial software ‘‘Origin6’’ was used. The Software used has the capability of performing nonlinear curve fitting to user input functions using a Levenberg–Marquardt iteration algorithm. At each iteration, the fitter computes the variance–Covariance matrix using its value from the previous iteration. This matrix depends on: the fitting function; the number of parameters; the dataset assignments. If any of these properties are altered, the current variance–covariance matrix is unusable for the altered properties, which means that the fitting session has to end. 4.1.3. Geothermal properties measurement The GPM is a program developed at the Oak Ridge National Laboratory to determine thermal properties of from short term field test data. The program makes use of a parameter-estimation-based method in combination with a 1-D numerical model developed by Shonder and Beck [14]. The numerical model relies on the cylinder source model considering the two pipes of the U-loop as a single cylinder. Thermal resistances present in the real problem are accounted for by adding to the model a thin film with resistance but no heat capacity and a layer of grout which may have thermal properties different from that of the surrounding soil (Fig. 2). Moreover, because the model represents the transient heat conduction in the borehole it accounts for time-varying heat inputs.

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Fig. 2. Schematic representation of the borehole heat exchanger model used in the 1-D numerical model [14].

4.2. Comparison between results 4.2.1. Slope determination Fig. 3 depicts the time evolution of the variables considered in the data evaluation. The fluctuations in thermal power injected are clearly visible. Some of the main features exhibited correlate with ambient temperature fluctuation in what is called as ‘‘ambient coupling’’. As shown by Eq. (4), the thermal conductivity is related to the slope of the resulting line in a logarithmic time plot of the mean fluid temperature in the BHE. Fig. 4a shows such a graphical representation for the entire time span of the test. Superimposed is regression line representing Eq. (4) is superimposed. Furthermore, because the approximate solution used in deriving the method approaches the exact solution for large times, part of the data set must not be considered in the evaluation. For the characteristics of the BHE under study, ruling out the first 15 h of data is more than sufficient to satisfy the time criteria set by Eq. (2). Also shown in Fig. 4a is the time interval of data finally subject to evaluation. A zoomed view of this evaluation interval and the slope of the associated regression line are detailed in Fig. 4b. Resulting values for the thermal conductivity and the borehole thermal resistance are 1.8 W/(m K) and 0.3 m K/W, respectively. 4.2.2. Two-variable parameter Fig. 5 is a plot of the resulting non-linear fitting curve superimposed to the experimental data (chi square is defined as the sum of the squares of the deviations of the theoretical curve from the experimental points). The inset presents the summary of results with the values of the two variable parameters, k ¼ 1:749 W=ðm KÞ and Rb ¼ 0:299 m K=W. 4.2.3. Geothermal properties measurement The results of the analysis using the GPM software are presented in Fig. 6. The mean fluid temperature predicted by LSM Eq. (4) is superimposed. Owing to

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Fig. 3. Time response of the system. Only variables considered in the data evaluation are shown.

the transient nature of the model, the entire data set is used in the analysis. The residuals (absolute errors) between predictions and experimental points are shown in the lower part of the graph with GPM values very close to zero. Relative large absolute errors can be observed during early stages of the test (between 0 and 10 h) possibly due to differences between real BHE response and that predicted by the model. Resulting values for the thermal conductivity and the borehole thermal resistance are 2.35 W/(mK) and 0.32 m K/W, respectively. A comparison between results is presented in Table 3.

5. Ambient coupling Despite provisions taken regarding thermal insulation of the hydraulic circuit, ambient coupling was observed. Fig. 7 depicts the simple energy model proposed to account for heat exchange between the different hot parts of the system and the surrounding environment. For simplicity, the system is considered as composed of two main parts: hydraulics (TED and connection pipes to borehole) and the BHE itself. TED is just a name given to the mobile unit carrying the hydraulics and measuring equipment used in TRTs. Hence, the simplified energy balance can be

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Fig. 4. Logarithmic time plot (a) of the mean fluid temperature for the entire length of the test; (b) zoomed view of the data interval, subject to evaluation.

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Fig. 5. Response test data and fitted curved. The inset presents the resulting values for k and Rb after the two-variable parameters fitting is applied.

written as: Q0 ¼ Qe  q

ð6Þ

Assuming that the hydraulic unit is at the mean fluid temperature, the rate of system heat loss to the surrounding can be expressed by: q ¼ U ðTf  Tamb Þ Therefore, the useful power delivered to the borehole is given by:   Q0 ¼ Qe  U Tf  Tamp

ð7Þ

ð8Þ

Making another assumption which in principle should hold true, that is, Q0 ¼ Qth , and substituting Eq. (8) into Eq. (4) leads to:     ½Qe  UðTf  Tamb Þ 4kt ½Qe  UðTf  Tamb Þ ln 2 Rb Tf ¼ c þ 4pkH r C H þ Tsur

ð9Þ

All parameters involved in this equation are known except for the overall heat transfer coefficient of the system. In principle, if made a variable parameter it can be determined by curve fitting using Eq. (9) as fitting function. Fig. 8 shows the experimental mean fluid temperature (thick smooth line) and predicted by Eq. (9) (thin line) with the overall heat transfer coefficient as fitting variable. Both curves are in fairly good agreement except for night hours when

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Fig. 6. System response using k and Rb values calculated by GPM program and the slope determination method.

electric power was neither controlled nor measured. For the purpose of modelling it was assumed that power remained constant over the night and equal to the mean value between last reading of the day and first reading of next day. A contrasting fact observable during night time is that the temperature predicted by the model reaches a minimum, resembling the pattern of the ambient temperature whilst the experimental fluid temperature (thick line) rises to maximum (circle and arrow) strongly suggesting a power-grid related behaviour. It is a known fact that during night time, voltage in the grid increases due to lower consumption. As a concluding remark, a good correlation observed between experimental and predicted values was obtained for a value of U ¼ 5:3 W=K.

Table 3 Comparison between results using different evaluation methods Evaluation method

k (W/m k)

Rb (m K/W)

Slope determination GPM Two-parameter fitting

1.8 2.35 1.749

0.3 0.32 0.299

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Fig. 7. Energy exchange model applied to account for the ambient coupling present during test.

6. Hours-off and length of test analysis As already mentioned, the reason for discarding initial data points from the original set derives from the fact that the solution used for data evaluation is an approximation applicable for times satisfying the criteria at=r2 > 5.

Fig. 8. Time evolution of mean fluid temperatures; experimental and predicted by the ambient coupling energy model.

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Table 4 Results of the hours-off analysis for sets of data intervals beginning at the hour-off point Hours-off (h)

Slope

k (W/m K)

Rb (m K/W)

7 10 15 20 25 30 Average

3.0182 3.0236 2.9731 2.9776 2.9948 2.9629

1.78 1.77 1.80 1.80 1.79 1.81 1.79

0.304 0.304 0.304 0.304 0.303 0.303 0.30

To assess how the start point (hours-off) of the evaluation data interval affects the values of the thermal conductivity and the borehole thermal resistance, a series of evaluations were performed on intervals with same end point but different hours-off at the beginning. The results are presented in Table 4. It can be seen in the table that in the worst scenario, the dispersion around the average is 1.1% for the thermal conductivity and 1.3% for the thermal resistance. 7. TRNSYS simulation The response test was further studied using TRNSYS TYPE 141 VERTICAL GROUND HEAT EXCHANGER [15]. This subroutine models a vertical heat exchanger that interacts thermally with the ground. The program assumes that the boreholes are placed uniformly within a cylindrical storage volume of ground (Fig. 9). There is convective heat transfer within the pipes, and conductive heat

Fig. 9. TRNSYS description of the U-Tube Ground Heat Exchanger (taken from the TYPE 141 technical data sheet).

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transfer to the storage volume. The temperature in the ground is calculated from three parts; a global temperature, a local solution, and a steady-flux solution. The model is a hybrid model, which uses the numerical method for the local and global problems and uses the analytical solution to superimpose the solution from the steady-flux part. For our particular case of one BHE, the volume of the storage region was defined as a cylinder of 1 m radius and depth equal to that of the actual BHE. Although TYPE 141 allows several ground layers to be considered, only one layer was assumed for the simulation. The program was fed with measured data on BHE inlet and outlet fluid temperature as well as ambient temperature. It might be pointed out that outlet fluid temperature was exclusively used for comparison with predicted outlet temperature in graphical presentation of results. Fig. 10 presents the results of the TRNSYS simulation. The agreement between experimental and TRNSYS simulated outlet temperature is remarkable. The graph also shows energy rates through the boundaries of the storage region and the evolution of the mean storage temperature. Top losses occurred during night reached in some cases 17% of the thermal energy injection rate. This is understandable considering no thermal insulation has been provided on top of the store, that is, the distance between the soil surface and the top of the ground heat exchanger is zero (d ¼ 0 in Fig. 9). Moreover, side

Fig. 10. Thermal response simulated using TRNSYS TYPE 141. Also shown are the rate of energy losses through the boundaries of the storage and the rise in the average storage temperature.

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energy losses (Q_s in Fig. 10) are appreciable only after 156 h from start of test indicating that the thermal wave may have reached the lateral side of the store. It is worth mentioning that the zigzag behavior exhibited by these side energy losses is a result of the dependency of the mathematical model (TYPE 141) on the thermal conductivity. Although k ¼ 2:15 W=ðm KÞ leads to a smooth line the difference between experimental and simulation outlet temperatures grows. The minimal difference is obtained with k ¼ 1:8 W=ðm KÞ. 8. Conclusions From the experience accumulated and from the results detailed above we draw the following conclusions: – The effective values of 1.8 W/(mK) and 0.3 mK/W were determined for the thermal conductivity and borehole thermal resistance, respectively. – The application of the classical slope determination and/or two-variable parameter fitting can be used as a fast and reliable tool for data evaluation. – The accuracy of the evaluation depends on the care taken when performing the test. Important aspects are reliable temperature measurements, constant power supply, a proper determination of undisturbed underground temperature and to weather-proof the system as much as possible. – The value of the thermal conductivity was quite insensitive to the hours-off condition but exhibited an oscillatory behavior regarding the length of test condition. Large relative error for short tests converging for test lengths over 120 h was the trend of the thermal conductivity when compared to the 1.8 W/(m K) expected value. – The fluctuations exhibited by the experimental curve are mainly governed by corresponding fluctuations of ambient temperature and by fluctuations of electric power supply specially during night hours. – An overall heat loss coefficient of 5.3 W/K was determined applying ambient coupling model based on an energy balance between the hot parts of the system and the surrounding environment. – This first experience represents a step towards a more detailed study on thermal properties of the soil in different sites in Chile and Argentina with a view to possible practical applications of underground thermal energy storage in the region. References [1] Mogensen P. Fluid to duct wall heat transfer in duct system heat storages. Proceedings of the International Conference on Subsurface Heat Storage in Theory and Practice, Stockholm, Sweden, June 6–8. 1983, p. 652–7. [2] Eklo¨f C, Gehlin S. TED—a mobile equipment for thermal response test. Master’s thesis 1996:198E. Sweden: Lulea˚ University of Technology; 1996. [3] Gehlin S, Nordell B. Thermal response test—a mobile equipment for determining thermal resistance of borehole. Proceedings of Megastock 1997, Seventh International Conference on Thermal Energy Storage, Sapporo, Japan, 18–20 June, vol. 1. 1997, p. 103–8.

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[4] Austin WA. Development of an in-situ system for measuring ground thermal properties. Master’s thesis. Stillwater, OK: Oklahoma State University; 1998. [5] Hellstro¨m G. Ground heat storage. Thermal analysis of duct storage systems. Part I theory. Lund, Sweden: Department of Mathematical Physics, University of Lund; 1991. p. 148–54. [6] Gehlin S. Thermal response test—in-situ measurements of thermal properties in hard rock. Licentiate thesis, Division of Water Resources Engineering, Department of Environmental Engineering, Lulea˚ University of Technology, vol. 37; 1998. p. 1–10. [7] Kavanaugh SP, Rafferty K. Ground-source heat pumps: design of geothermal systems for commercial and institutional buildings. Atlanta: ASHRAE Inc; 1997 [p. 22–31]. [8] Hellstro¨m G, Kjellsson E. Laboratory measurement of heat transfer properties for different types of borehole heat exchangers. Proceedings of Terrastock 2000, Eighth International Conference on Thermal Energy Storage, Stuttgart, August 28–September 1, vol. 1. 2000, p. 183–8. [9] Sanner B, Reuss M, Mands E, Mu¨ller J. Thermal response test—experiences in Germany. Proceedings of Terrastock 2000, eighth International Conference on Thermal Energy Storage, Stuttgart, August 28–September 1, vol. 1. 2000, p. 177–82. [10] Paksoy H, Gurbuz Z, Turgut B, Dikici D, Evliya H. Aquifer thermal storage (ATES) for airconditioning of a supermarket in Turkey. Proceedings of World Renewable Energy Congress-VII 2002, Cologne, Germany, 29 June–5 July. 2002 [10_n66.pdf]. [11] Georgiev A, Ortiz A, Roth P. Underground thermal energy storage—Chilean experience. Proceedings of World Renewable Energy Congress-VII 2002, Cologne, Germany, 29 June–5 July. 2002 [05_N39.pdf]. [12] Busso A, Reuss M. Operating experiences with geothermal response tests. Proceedings of FUTURESTOCK 2003 Ninth International Conference on Thermal Energy Storage, 1–4 September. 2003. [13] Carslaw HS, Jaeger JC. Conduction of heat in solids, 2nd ed. Oxford: Clarendon Press; 1993. [14] Shonder JA, Beck JV. Determining effective soil formation properties from field data using a parameter estimations technique. ASHRAE Trans 1999;105(1):458–66. [15] Hellstrom G. Duct ground heat storage model, Manual for Computer Code. Sweden: Department of Mathematical Physics, University of Lund; 1989.

First in situ determination of ground and borehole ...

for implementing the TRT was prepared at the ''Solar Energy Laboratory'' of the Technical ... tivity measurement system appeared in Sweden [2,3] and the USA [4]. ..... Licentiate thesis, Division of Water Resources Engineering, Department of ...

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MILLENNIUM32 software (version 3.05.01) was used for data acquisition and ... the linearity, sensitivity, precision and accuracy for each ana- lyte [16].

Electrochemical determination of dopamine and ...
and KCl (5 0 0), where the data in the brackets were the concen- tration ratios. ... Aunano-ME responds well for the recovery of spiked DA with high sensitivity ...

DENR Borehole Project 2016 requirements.pdf
Administrative Rules of South Dakota 74:02:04. A list of drillers licensed to drill in South Dakota. can be found at: http://denr.sd.gov/des/wr/dbdrillerlist.aspx.