Lehrstuhl

Energie

Prof. Dr.-Ing. H. Spliethoff

Systeme

The Organic Rankine Cycle – Power Production from Low Temperature Heat

Hartmut Spliethoff, Andreas Schuster Institute for Energy Systems Technische Universität München

Electricity generation, combined heat and power Strasbourg, 14 -16 September 2006

Lehrstuhl

Energie

Prof. Dr.-Ing. H. Spliethoff

Systeme

Contents

• Introduction – History… – Recapitulation Clausius Rankine Cycle

• State of the Art Applications – Biomass Combustion – Geothermal Power Plants

• Innovative Applications – Solar Desalination with Organic Rankine Cycle – Waste-heat recovery from biomass digestion plants

• Conclusion and Outlook

Electricity generation, combined heat and power Strasbourg, 14 -16 September 2006

2

Lehrstuhl

Energie

Prof. Dr.-Ing. H. Spliethoff

Systeme

Who was the Rankine - cycle’s “father” ? William John Macquorn Rankine * 5th July 1820 † 24th December 1872 • Scottish physicist and engineer • one of the founders of thermodynamics

WJM Rankine

• important contributions to the theory of steam engine

Electricity generation, combined heat and power Strasbourg, 14 -16 September 2006

3

Lehrstuhl Prof. Dr.-Ing. H. Spliethoff

Energie Systeme

Assembly of a steam power station

Boiler House (steam generator)

Turbine House

Cooling Towers

(steam turbine, condenser, generator)

Boiler

Steam Turbine

G Generator

Condenser

Coal Stockyard

Feed Pump

Jürgen Karl

Flue Gas Cleaning M(dust removal, nitric oxide removal, desulphurization)

Electricity generation, combined heat and power Strasbourg, 14 -16 September 2006

4

Lehrstuhl Prof. Dr.-Ing. H. Spliethoff

Energie Systeme

Power range and efficiency of common power machines for external combustion 1000

power range [MW]

Steam Power Plants 100 10

Organic Rankine Cycle

1

Steam Engine

0,1

Stirling Engine Jürgen Karl, Dezentrale Energiesysteme

0,01 0

20

40

60

80

efficiency [%] Electricity generation, combined heat and power Strasbourg, 14 -16 September 2006

5

Lehrstuhl

Energie

Prof. Dr.-Ing. H. Spliethoff

Systeme

The Organic Rankine Cycle – an application for small power range The ORC uses organic substances instead of water as working fluid • Silicone Oils • Hydrocarbons • Fluorocarbons water

organic fluids

Organic fluids lead to • higher turbine efficiencies due to the higher mass flow (leakage ↓) • low maintenance operation • good part load behavior Electricity generation, combined heat and power Strasbourg, 14 -16 September 2006

6

Lehrstuhl Prof. Dr.-Ing. H. Spliethoff

Energie Systeme

The Organic Rankine Cycle – an application for small power range and external heat source

200 500

Generator

50 100

0 0

District Heating Network

6 1

1 Feed Pump Feed Pump

M

0 0

Cooling Tower Condenser

(dust removal, nitric oxide M removal, desulphurization)

22

100 200

5 Condenser

33 44

3

3

10 bar

5

10 bar

11

11

00 0,0 1,0

00

5

5 bar

6

1 bar

p=1 bar p=0,05 bar

0,8

2

5 G

300

0,8

biomass boiler geothermal heat waste heat …

Turbine

Generator

25 bar

22

100 bar

0,,6 6

3 Steam

G

44

0,4 0 ,4

Boiler

2 3 4

400 150

x=0 x= ,2 0,2

Heat 4 Exchanger

temperature [° [°C] temperature C]

Turbine

6

55

2,0 4,0 6,0 8,0 10,0 1,2 1,4 1,6 1,8 2,0 spezific spezific entropy entropy [kJ/kgK] [kJ/kgK]

Availaible in a power range up to 1500 kW… MW…

Electricity generation, combined heat and power Strasbourg, 14 -16 September 2006

7

Lehrstuhl

Energie

Prof. Dr.-Ing. H. Spliethoff

Systeme 200

25 bar

4

3

2

100

10 bar

55

5 bar

1

5

6 0,8

0

0,6

50

x= 0 ,2

G

150

0, 4

temperature [°C]

ORC with without recuperator recuperator

6

p=1 bar

0 1,0

6

M

1,2 1,4 1,6 1,8 spezific entropy [kJ/kgK]

2,0

• Expansion does end in the area of superheated steam 5 • Sensible Heat of steam ( 5 - 6 ) can be used for preheating the liquid working fluid

Electricity generation, combined heat and power Strasbourg, 14 -16 September 2006

8

Lehrstuhl

Energie

Prof. Dr.-Ing. H. Spliethoff

Systeme

State of the Art Applications

Electricity generation, combined heat and power Strasbourg, 14 -16 September 2006

9

Lehrstuhl

Energie

Prof. Dr.-Ing. H. Spliethoff

Systeme

ORC Unit from Turboden, Brescia Italy • Units from 500 kW up to 1500 kW available

Rekuperator Condenser

• Standardized Product

Evaporator

Turbine Generator

Feed Pump

• Units are delivered completely assembled to installation site

Electricity generation, combined heat and power Strasbourg, 14 -16 September 2006

10

Lehrstuhl

Energie

Prof. Dr.-Ing. H. Spliethoff

Systeme

Sauerlach – 700 kWel

Biomass Combustion Thermo oil loop G

Organic Rankine Cycle

Electricity generation, combined heat and power Strasbourg, 14 -16 September 2006

Toblach – 1500 kWel

Fußach – 1100 kWel 11

Lehrstuhl Prof. Dr.-Ing. H. Spliethoff

Energie Systeme

Insertion • dependency of electric efficiency of exhaust gas losses of biomass boiler • flow temperature / return temperature thermo oil 270 °C / 220 °C

Electric Efficiency 10…12 % Manufacturer information of 16…18 % don’t include the furnace

Electricity generation, combined heat and power Strasbourg, 14 -16 September 2006

12

Lehrstuhl Prof. Dr.-Ing. H. Spliethoff

Energie

Geothermal Power Plants ORC System

Return Cooler 28°C

Water processing

www.geothermie.de

Systeme

15-110 m³/h

Altheim 1000 kWel

21°C, 120-395 m³/h

Well

www.geothermie.de

Neustadt-Glewe 210 kWel 98°C

Bore Hole

Injection Bore Hole

Electricity generation, combined heat and power Strasbourg, 14 -16 September 2006

13

Lehrstuhl

Energie

Prof. Dr.-Ing. H. Spliethoff

Systeme

Innovative applications

Electricity generation, combined heat and power Strasbourg, 14 -16 September 2006

14

Lehrstuhl

Energie Systeme

Prof. Dr.-Ing. H. Spliethoff

Innovative stand-alone solar desalination system with an Organic Rankine Cycle

Collector Loop

Organic Rankine Cycle Electricity generation, combined heat and power Strasbourg, 14 -16 September 2006

Osmosis Process 15

Lehrstuhl

Energie

Prof. Dr.-Ing. H. Spliethoff

Systeme

Design Criteria for ORC with solar heat • Scroll expander for mechanical power in the range of 10 kW

• Different working fluids offer nearly the same efficieny • Fluid with efficiency maximum at the lowest posssible temperature fits best

cycle efficiency [%]

• Scroll expander is a positve displacement expansion machine 5,6 R227 R245fa 5,4 5,2 R236fa 5,0 4,8 R134a 4,6 4,4 4,2 4,0 50 75 100 125 150 live steam temperature [°C]

Electricity generation, combined heat and power Strasbourg, 14 -16 September 2006

16

Lehrstuhl

Energie

Prof. Dr.-Ing. H. Spliethoff

Systeme

Status of the project • The project is succesfully finished • The expander efficiency is between 60 and 70 % over a wide operation range • The cycle efficiency is around 4 % • The fresh water production is approximately 320 l/h with a thermal input of 35 kW

The research was done in the framework of the project RO-Solar-Rankine (COOPCT-2003-507997) funded by the European Comission. Therefore the TU München is much obliged.

Electricity generation, combined heat and power Strasbourg, 14 -16 September 2006

17

Lehrstuhl

Energie Systeme

Prof. Dr.-Ing. H. Spliethoff

Waste-heat recovery from biomass digestion recovery with low temperature ORC plants

• Gainful use of the excess heat of the IC engine is important for the economic and energetic efficiency • Only 20…25 % of the waste heat of the engine is needed for heating the digester • The characteristics of heat demand and the location of the digestion plants is hindering for the use of waste heat in district heating networks enhanced electricity production by the application of ORC Electricity generation, combined heat and power Strasbourg, 14 -16 September 2006

Organic Waste Energy Crops

Manure

Desulphurization Biogas

Fermenter

Grid

IC engine

Biogas tank

ORC System 18

Lehrstuhl

Energie Systeme

Prof. Dr.-Ing. H. Spliethoff

Case Study for biomass digestion plant Thermo oil loop Test Rig at TUM

IC engine

Organic Rankine Cycle Electricity generation, combined heat and power Strasbourg, 14 -16 September 2006

19

Lehrstuhl

Energie Systeme

Prof. Dr.-Ing. H. Spliethoff

Case Study for biomass digestion plant

• Combustion Engine 555 kW Deutz TCG 2016 V12 • Electrical Power 537 kWel • Exhaust gas temperature of ~ 490 °C • Additional Power production of 35 kWel equivalent to an efficiency gain of 2.6 % • With an interest rate of 5 % and 7.500 full load hours electricity production cost of 5.65 €Ct/kWh can be reached

Electricity generation, combined heat and power Strasbourg, 14 -16 September 2006

5

Ct O.R.

6C

t t 7C 8C

t

9C

t

20

Lehrstuhl

Energie

Prof. Dr.-Ing. H. Spliethoff

Systeme

Conclusions: • Organic Rankine Cycles are a modification of the well known Clausius Rankine Cycle • The use of organic fluids offer various advantages • The ORC technology for electricity production from biomass and geothermal heat is state of the art • ORCs are also suitable for waste-heat recovery and power production from solarthermal heat – these applications are subject of further research • ORC linked with Reverse Osmosis is a promising possibility for seawater desalination

Electricity generation, combined heat and power Strasbourg, 14 -16 September 2006

21

40-slides-0-Spliethoff.pdf

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